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イソプロピルピペリジンジチオカルバミン酸を用いた新規一次元配位高分子の合成とキャリア輸送特性
https://kindai.repo.nii.ac.jp/records/11303
https://kindai.repo.nii.ac.jp/records/113039d9124cb-62ac-47e4-bfc3-597bbc7f7de6
名前 / ファイル | ライセンス | アクション |
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AN10074306-20150228-0035.pdf (3.5 MB)
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Item type | ☆紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2015-06-09 | |||||
タイトル | ||||||
タイトル | イソプロピルピペリジンジチオカルバミン酸を用いた新規一次元配位高分子の合成とキャリア輸送特性 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Synthesis and Carrier Transport properties of a New Mixed-valence 1-D Coordination Polymer with an Isopropyl Dithiocarbamate Ligand | |||||
著者 |
中橋, 裕貴
× 中橋, 裕貴× 鈴木, 慎平× 太田, 悠輔× 大久保, 貴志× 前川, 雅彦× 黒田, 孝義 |
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言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題 | mixed-valence coordination polymer, dithiocarbamate ligand, absorption spectra, magnetic susceptibility, electric conductivity | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
著者(英) | ||||||
en | ||||||
NAKAHASHI, Yuuki | ||||||
著者(英) | ||||||
en | ||||||
SUZUKI, Shimpei | ||||||
著者(英) | ||||||
en | ||||||
OTA, Yusuke | ||||||
著者(英) | ||||||
en | ||||||
OKUBO, Takashi | ||||||
著者(英) | ||||||
en | ||||||
MAEKAWA, Masahiko | ||||||
著者(英) | ||||||
en | ||||||
KURODA-SOWA, Takayoshi | ||||||
著者 所属 | ||||||
近畿大学 | ||||||
著者 所属 | ||||||
近畿大学 | ||||||
著者 所属 | ||||||
近畿大学 | ||||||
著者 所属 | ||||||
近畿大学 : 科学技術振興機構 | ||||||
著者 所属 | ||||||
近畿大学 | ||||||
著者 所属 | ||||||
近畿大学 | ||||||
著者所属(翻訳) | ||||||
School of Science and Engineering, Kinki University | ||||||
著者所属(翻訳) | ||||||
School of Science and Engineering, Kinki University | ||||||
著者所属(翻訳) | ||||||
School of Science and Engineering, Kinki University | ||||||
著者所属(翻訳) | ||||||
School of Science and Engineering, Kinki University : PRESTO, Japan Science and Technology Agency | ||||||
著者所属(翻訳) | ||||||
Research Institute for Science and Technology, Kinki University | ||||||
著者所属(翻訳) | ||||||
School of Science and Engineering, Kinki University | ||||||
版 | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 名前 | ||||||
出版者 | 近畿大学理工学総合研究所 | |||||
書誌情報 |
理工学総合研究所研究報告 en : Annual reports by Research Institute for Science and Technology 巻 27, p. 35-41, 発行日 2015-02-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 09162054 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | [Abstract]A novel mixed-valence Cu(I)-Cu(II) coordination polymer having an infinite one-dimensional(1D) structure, [Cu^I_2Cu^IIBr_2(iPr-pip-dtc)_2]_n (1) (iPr-pip-dtc- = 4-isopropylpiperidine dithiocarbamate), has been prepared and structurally characterized via X-ray diffraction. Magnetic studies indicate that this complex including copper(II) ions exhibits a weak ferromagnetic interaction (θ = 0.52 K) between the unpaired electrons of the copper(II) ions through the diamagnetic Cu(I)-Br chains. The carrier transport properties of 1 are investigated using an impedance spectroscopy technique. The impedance spectroscopy reveals that this complex exhibits intriguing semiconducting properties at a small activation energy (E_a = 0.278 eV ). | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |