{"created":"2023-06-20T16:40:54.835345+00:00","id":11303,"links":{},"metadata":{"_buckets":{"deposit":"f0da722e-cd6c-424e-b3f5-f5bc6435f353"},"_deposit":{"created_by":3,"id":"11303","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"11303"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00011303","sets":["14:923:2091:2092","21:3039:3558:3580"]},"author_link":["21877","21873","21875","21874","21878","21876"],"item_2_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-02-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"41","bibliographicPageStart":"35","bibliographicVolumeNumber":"27","bibliographic_titles":[{"bibliographic_title":"理工学総合研究所研究報告"},{"bibliographic_title":"Annual reports by Research Institute for Science and Technology","bibliographic_titleLang":"en"}]}]},"item_2_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"[Abstract]A novel mixed-valence Cu(I)-Cu(II) coordination polymer having an infinite one-dimensional(1D) structure, [Cu^I_2Cu^IIBr_2(iPr-pip-dtc)_2]_n (1) (iPr-pip-dtc- = 4-isopropylpiperidine dithiocarbamate), has been prepared and structurally characterized via X-ray diffraction. Magnetic studies indicate that this complex including copper(II) ions exhibits a weak ferromagnetic interaction (θ = 0.52 K) between the unpaired electrons of the copper(II) ions through the diamagnetic Cu(I)-Br chains. The carrier transport properties of 1 are investigated using an impedance spectroscopy technique. The impedance spectroscopy reveals that this complex exhibits intriguing semiconducting properties at a small activation energy (E_a = 0.278 eV ).","subitem_description_type":"Abstract"}]},"item_2_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学理工学総合研究所"}]},"item_2_source_id_22":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09162054","subitem_source_identifier_type":"ISSN"}]},"item_2_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"NAKAHASHI, Yuuki"},{"subitem_text_language":"en","subitem_text_value":"SUZUKI, Shimpei"},{"subitem_text_language":"en","subitem_text_value":"OTA, Yusuke"},{"subitem_text_language":"en","subitem_text_value":"OKUBO, Takashi"},{"subitem_text_language":"en","subitem_text_value":"MAEKAWA, Masahiko"},{"subitem_text_language":"en","subitem_text_value":"KURODA-SOWA, Takayoshi"}]},"item_2_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学"},{"subitem_text_value":"近畿大学"},{"subitem_text_value":"近畿大学"},{"subitem_text_value":"近畿大学 : 科学技術振興機構"},{"subitem_text_value":"近畿大学"},{"subitem_text_value":"近畿大学"}]},"item_2_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"School of Science and Engineering, Kinki University"},{"subitem_text_value":"School of Science and Engineering, Kinki University"},{"subitem_text_value":"School of Science and Engineering, Kinki University"},{"subitem_text_value":"School of Science and Engineering, Kinki University : PRESTO, Japan Science and Technology Agency"},{"subitem_text_value":"Research Institute for Science and Technology, Kinki University"},{"subitem_text_value":"School of Science and Engineering, Kinki University"}]},"item_2_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"中橋,  裕貴"},{"creatorName":"ナカハシ, ユウキ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"鈴木,  慎平"},{"creatorName":"ススギ, シンぺイ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"太田,  悠輔"},{"creatorName":"オオタ, ユウスケ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"大久保,  貴志"},{"creatorName":"オオクボ, タカシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"前川,  雅彦"},{"creatorName":"マエカワ, マサヒコ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"黒田,  孝義"},{"creatorName":"クロダ, タカヨシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-19"}],"displaytype":"detail","filename":"AN10074306-20150228-0035.pdf","filesize":[{"value":"3.5 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"AN10074306-20150228-0035.pdf","url":"https://kindai.repo.nii.ac.jp/record/11303/files/AN10074306-20150228-0035.pdf"},"version_id":"276805df-1ac5-42ff-9423-69d26dfaa096"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"mixed-valence coordination polymer","subitem_subject_scheme":"Other"},{"subitem_subject":"dithiocarbamate ligand","subitem_subject_scheme":"Other"},{"subitem_subject":"absorption spectra","subitem_subject_scheme":"Other"},{"subitem_subject":"magnetic susceptibility","subitem_subject_scheme":"Other"},{"subitem_subject":"electric conductivity","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"イソプロピルピペリジンジチオカルバミン酸を用いた新規一次元配位高分子の合成とキャリア輸送特性","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"イソプロピルピペリジンジチオカルバミン酸を用いた新規一次元配位高分子の合成とキャリア輸送特性"},{"subitem_title":"Synthesis and Carrier Transport properties of a New Mixed-valence 1-D Coordination Polymer with an Isopropyl Dithiocarbamate Ligand","subitem_title_language":"en"}]},"item_type_id":"2","owner":"3","path":["2092","3580"],"pubdate":{"attribute_name":"公開日","attribute_value":"2015-06-09"},"publish_date":"2015-06-09","publish_status":"0","recid":"11303","relation_version_is_last":true,"title":["イソプロピルピペリジンジチオカルバミン酸を用いた新規一次元配位高分子の合成とキャリア輸送特性"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T20:41:51.594886+00:00"}