@article{oai:kindai.repo.nii.ac.jp:00011303, author = {中橋, 裕貴 and 鈴木, 慎平 and 太田, 悠輔 and 大久保, 貴志 and 前川, 雅彦 and 黒田, 孝義}, journal = {理工学総合研究所研究報告, Annual reports by Research Institute for Science and Technology}, month = {Feb}, note = {[Abstract]A novel mixed-valence Cu(I)-Cu(II) coordination polymer having an infinite one-dimensional(1D) structure, [Cu^I_2Cu^IIBr_2(iPr-pip-dtc)_2]_n (1) (iPr-pip-dtc- = 4-isopropylpiperidine dithiocarbamate), has been prepared and structurally characterized via X-ray diffraction. Magnetic studies indicate that this complex including copper(II) ions exhibits a weak ferromagnetic interaction (θ = 0.52 K) between the unpaired electrons of the copper(II) ions through the diamagnetic Cu(I)-Br chains. The carrier transport properties of 1 are investigated using an impedance spectroscopy technique. The impedance spectroscopy reveals that this complex exhibits intriguing semiconducting properties at a small activation energy (E_a = 0.278 eV )., application/pdf}, pages = {35--41}, title = {イソプロピルピペリジンジチオカルバミン酸を用いた新規一次元配位高分子の合成とキャリア輸送特性}, volume = {27}, year = {2015}, yomi = {ナカハシ, ユウキ and ススギ, シンぺイ and オオタ, ユウスケ and オオクボ, タカシ and マエカワ, マサヒコ and クロダ, タカヨシ} }