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π-π相互作用により自己集積化された6,6'-ジフェニル-4,4'-ビピリミジンを配位子とする新規な一次元銅(I)-エチレン錯体の合成および構造
https://kindai.repo.nii.ac.jp/records/11068
https://kindai.repo.nii.ac.jp/records/11068dacfb114-2524-4b44-9d0e-ae0e34d10889
名前 / ファイル | ライセンス | アクション |
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AN10074306-20100228-0035.pdf (1.6 MB)
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Item type | ☆紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2010-08-05 | |||||
タイトル | ||||||
タイトル | π-π相互作用により自己集積化された6,6'-ジフェニル-4,4'-ビピリミジンを配位子とする新規な一次元銅(I)-エチレン錯体の合成および構造 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Novel Cu (I) ethylene complex with 6,6'-dipheny1-4,4'-bipyrimidine one-dimensionally self-assembled by an intermolecular π-π stacking interaction | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | Novel Cu (I) ethylene complex with 6,6'-dipheny1-4,4'-bipyrimidine one-dimensionally self-assembled by an intermolecular π-π stacking interaction | |||||
著者 |
富永, 登志
× 富永, 登志× 前川, 雅彦× 大久保, 貴志× 黒田, 孝義× 宗像, 惠 |
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言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題 | Copper(I) complexes, Ethylene adducts, N ligands, Nitrogen heterocycles, π-π stacking interactions | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
著者(英) | ||||||
en | ||||||
TOMINAGA, Toshi | ||||||
著者(英) | ||||||
en | ||||||
MAEKAWA, Masahiko | ||||||
著者(英) | ||||||
en | ||||||
OKUBO, Takashi | ||||||
著者(英) | ||||||
en | ||||||
KURODA-SOWA, Takayoshi | ||||||
著者(英) | ||||||
en | ||||||
MUNAKATA, Megumu | ||||||
著者 所属 | ||||||
Department of Chemistry, Kinki University | ||||||
著者 所属 | ||||||
Research Institute for Science and Technology, Kinki University | ||||||
著者 所属 | ||||||
Department of Chemistry, Kinki University | ||||||
著者 所属 | ||||||
Department of Chemistry, Kinki University | ||||||
著者 所属 | ||||||
Department of Chemistry, Kinki University | ||||||
版 | ||||||
出版タイプ | NA | |||||
出版タイプResource | http://purl.org/coar/version/c_be7fb7dd8ff6fe43 | |||||
出版者 名前 | ||||||
出版者 | 近畿大学理工学総合研究所 | |||||
書誌情報 |
理工学総合研究所研究報告 en : Annual reports by Research Institute for Science and Technology 号 22, p. 35-40, 発行日 2010-02-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 09162054 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Novel Cu(I)-Ph_2bpm/C_2H_4 adduct [Cu(Ph_2bpm)(C_2H_4)]NO_3 (Ph_2bpm=6,6’-diphenyl-4,4’-bipyrimidine) was prepared and it has been characterized by Xray crystallography. The Cu atom is coordinated by two N atoms in the chelate site of Ph_2bpm and C=C bond of C_2H_4 in the trigonal-planar geometry. It is interesting that 1D network structures are self-assembled by an intermolecular π-π stacking interaction between a phenyl ring and a phenyl ring in the neighboring Ph_2bpm. The X-ray and IR data supported the assumption that the contribution of the larger Cu(I)→C_2H_4 π-back donation bonding is induced by the electronreleasing phenyl group. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |