@article{oai:kindai.repo.nii.ac.jp:00011068,
 author = {富永,  登志 and 前川,  雅彦 and 大久保,  貴志 and 黒田,  孝義 and 宗像,  惠},
 issue = {22},
 journal = {理工学総合研究所研究報告, Annual reports by Research Institute for Science and Technology},
 month = {Feb},
 note = {Novel Cu(I)-Ph_2bpm/C_2H_4 adduct [Cu(Ph_2bpm)(C_2H_4)]NO_3 (Ph_2bpm＝6,6’-diphenyl-4,4’-bipyrimidine) was prepared and it has been characterized by Xray crystallography. The Cu atom is coordinated by two N atoms in the chelate site of Ph_2bpm and C＝C bond of C_2H_4 in the trigonal-planar geometry. It is interesting that 1D network structures are self-assembled by an intermolecular π-π stacking interaction between a phenyl ring and a phenyl ring in the neighboring Ph_2bpm. The X-ray and IR data supported the assumption that the contribution of the larger Cu(I)→C_2H_4 π-back donation bonding is induced by the electronreleasing phenyl group., application/pdf},
 pages = {35--40},
 title = {π-π相互作用により自己集積化された6,6'-ジフェニル-4,4'-ビピリミジンを配位子とする新規な一次元銅(I)-エチレン錯体の合成および構造},
 year = {2010},
 yomi = {トミナガ, トシ and マエカワ, マサヒコ and オオクボ, タカシ and ムナカタ, メグム}
}