{"created":"2023-06-20T16:40:43.655071+00:00","id":11068,"links":{},"metadata":{"_buckets":{"deposit":"c179e437-5d5d-430c-91e0-c00420c6aaa3"},"_deposit":{"created_by":3,"id":"11068","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"11068"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00011068","sets":["14:923:2091:2103","21:3039:3558:3559"]},"author_link":["21258","21255","21256","21254","21257"],"item_2_alternative_title_3":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Novel Cu (I) ethylene complex with 6,6'-dipheny1-4,4'-bipyrimidine one-dimensionally self-assembled by an intermolecular π-π stacking interaction"}]},"item_2_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-02-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"22","bibliographicPageEnd":"40","bibliographicPageStart":"35","bibliographic_titles":[{"bibliographic_title":"理工学総合研究所研究報告"},{"bibliographic_title":"Annual reports by Research Institute for Science and Technology","bibliographic_titleLang":"en"}]}]},"item_2_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Novel Cu(I)-Ph_2bpm/C_2H_4 adduct [Cu(Ph_2bpm)(C_2H_4)]NO_3 (Ph_2bpm＝6,6’-diphenyl-4,4’-bipyrimidine) was prepared and it has been characterized by Xray crystallography. The Cu atom is coordinated by two N atoms in the chelate site of Ph_2bpm and C＝C bond of C_2H_4 in the trigonal-planar geometry. It is interesting that 1D network structures are self-assembled by an intermolecular π-π stacking interaction between a phenyl ring and a phenyl ring in the neighboring Ph_2bpm. The X-ray and IR data supported the assumption that the contribution of the larger Cu(I)→C_2H_4 π-back donation bonding is induced by the electronreleasing phenyl group.","subitem_description_type":"Abstract"}]},"item_2_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学理工学総合研究所"}]},"item_2_source_id_22":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09162054","subitem_source_identifier_type":"ISSN"}]},"item_2_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"TOMINAGA, Toshi"},{"subitem_text_language":"en","subitem_text_value":"MAEKAWA, Masahiko"},{"subitem_text_language":"en","subitem_text_value":"OKUBO, Takashi"},{"subitem_text_language":"en","subitem_text_value":"KURODA-SOWA, Takayoshi"},{"subitem_text_language":"en","subitem_text_value":"MUNAKATA, Megumu"}]},"item_2_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"Department of Chemistry, Kinki University"},{"subitem_text_value":"Research Institute for Science and Technology, Kinki University"},{"subitem_text_value":"Department of Chemistry, Kinki University"},{"subitem_text_value":"Department of Chemistry, Kinki University"},{"subitem_text_value":"Department of Chemistry, Kinki University"}]},"item_2_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_be7fb7dd8ff6fe43","subitem_version_type":"NA"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"富永,  登志"},{"creatorName":"トミナガ, トシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"前川,  雅彦"},{"creatorName":"マエカワ, マサヒコ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"大久保,  貴志"},{"creatorName":"オオクボ, タカシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"黒田,  孝義"},{"creatorName":"&EMPTY&","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"宗像,  惠"},{"creatorName":"ムナカタ, メグム","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-19"}],"displaytype":"detail","filename":"AN10074306-20100228-0035.pdf","filesize":[{"value":"1.6 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"AN10074306-20100228-0035.pdf","url":"https://kindai.repo.nii.ac.jp/record/11068/files/AN10074306-20100228-0035.pdf"},"version_id":"2b2891aa-1fd6-4ab0-9528-c1101e42d519"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Copper(I) complexes","subitem_subject_scheme":"Other"},{"subitem_subject":"Ethylene adducts","subitem_subject_scheme":"Other"},{"subitem_subject":"N ligands","subitem_subject_scheme":"Other"},{"subitem_subject":"Nitrogen heterocycles","subitem_subject_scheme":"Other"},{"subitem_subject":"π-π stacking interactions","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"π-π相互作用により自己集積化された6,6'-ジフェニル-4,4'-ビピリミジンを配位子とする新規な一次元銅(I)-エチレン錯体の合成および構造","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"π-π相互作用により自己集積化された6,6'-ジフェニル-4,4'-ビピリミジンを配位子とする新規な一次元銅(I)-エチレン錯体の合成および構造"},{"subitem_title":"Novel Cu (I) ethylene complex with 6,6'-dipheny1-4,4'-bipyrimidine one-dimensionally self-assembled by an intermolecular π-π stacking interaction","subitem_title_language":"en"}]},"item_type_id":"2","owner":"3","path":["2103","3559"],"pubdate":{"attribute_name":"公開日","attribute_value":"2010-08-05"},"publish_date":"2010-08-05","publish_status":"0","recid":"11068","relation_version_is_last":true,"title":["π-π相互作用により自己集積化された6,6'-ジフェニル-4,4'-ビピリミジンを配位子とする新規な一次元銅(I)-エチレン錯体の合成および構造"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T20:42:46.140548+00:00"}