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ヘテロ金属メタラマクロサイクリック・配位高分子の構築と機能
https://kindai.repo.nii.ac.jp/records/18821
https://kindai.repo.nii.ac.jp/records/18821d4a313a7-8706-4132-9d73-e15969c64a75
名前 / ファイル | ライセンス | アクション |
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26410079seika.pdf (320.8 kB)
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Item type | 研究報告書 / Research Paper(1) | |||||
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公開日 | 2017-11-01 | |||||
タイトル | ||||||
タイトル | ヘテロ金属メタラマクロサイクリック・配位高分子の構築と機能 | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | Syntheses and functions of heterometallic metallomacrocycles and coordination polymers | |||||
著者 |
前川, 雅彦
× 前川, 雅彦 |
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言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題 | イリジウム錯体, ヒドリド錯体, 銀錯体, 異種金属錯体, 配位高分子, X線構造解析, NMR, 多座窒素配位子 | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_18ws | |||||
資源タイプ | research report | |||||
著者(英) | ||||||
en | ||||||
MAEKAWA, MASAHIKO | ||||||
著者 所属 | ||||||
近畿大学理工学総合研究所; 教授 | ||||||
著者所属(翻訳) | ||||||
Kindai University | ||||||
著者 役割 | ||||||
研究代表者 | ||||||
著者 外部リンク | ||||||
関連名称 | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-26410079/ | |||||
版 | ||||||
出版タイプ | NA | |||||
出版タイプResource | http://purl.org/coar/version/c_be7fb7dd8ff6fe43 | |||||
出版者 名前 | ||||||
出版者 | 近畿大学 | |||||
書誌情報 |
科学研究費助成事業研究成果報告書 (2016) p. 1-4, 発行日 2017 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | 研究成果の概要(和文):前駆Ir(III)-ヒドリド錯体と4-(2-ピリジル)ピリミジン(pprd),6,6'-ジメチル-4,4'-ビピリミジン(Me2bpm)および4,4'-ビキナゾリン(biqz)を反応させ,配位不飽和サイトを有する5つの錯体配位子Ir(III)-{pprd, Me2bpm, biqz}/H2/PPh3 (1~5)を合成した。続いて,これらIr(III)-ヒドリド錯体配位子とAgCF3COOを反応させ,3つの新規なヘテロ金属Ag(I)-Ir(III)ヒドリド配位高分子Ir(III)-Ag(I)-{pprd, Me2bpm,biqz}/H2/PPh3/CF3COO (6~8)を構築した。 研究成果の概要(英文):A new type of Ir(III) metalloligands containing an unsaturated nitrogen coordination site, [Ir(H)2(PPh3)2(pprd)]BF4 (1), [Ir(H)2(PPh3)2(Me2bpm)]BF4 (2), {[Ir(H)2(PPh3)2(Me2bpm)]PF6}4 (3), [Ir(H)2(PPh3)2(biqz)]BF4 (4) and [Ir(H)2(PPh3)2(biqz)]PF6 (5), have been prepared by the reactions of [Ir(H)2(PPh3)2(Me2CO)2]X (X = BF4 and PF6) with 4-(2-pyridyl)pyrimidine (pprd), 6,6'-dimethyl-4,4'-bipyrimidine (Me2bpm) and 4,4'-biquinazoline (biqz). Subsequently, three novel heterometallic Ag(I)-Ir(III) hydride coordination polymers, {[Ir(H)2(μ-pprd)(PPh3)2Ag(η-CF3COO)]BF4 }n (6), {[Ir(H)2(μ-biqz)(PPh3)2Ag2(μ-CF3COO)3] }n (7) and {[Ir(H)2(μ-Me2bpm)(PPh3)2Ag2(μ-CF3COO)2]PF6}n (8) have been reasonably constructed by the reactions of Ir(III) metalloligands 1, 3 and 5 with AgCF3COO. |
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内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 研究種目:基盤研究(C); 研究期間:2014~2016; 課題番号:26410079; 研究分野:化学; 科研費の分科・細目: | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | Research Paper | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |