{"created":"2023-06-20T16:47:11.392006+00:00","id":18821,"links":{},"metadata":{"_buckets":{"deposit":"ac4db8f0-8cc6-4776-b939-1413dc2fecc4"},"_deposit":{"created_by":3,"id":"18821","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"18821"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00018821","sets":["14:2667:4374"]},"author_link":["31812"],"item_8_alternative_title_3":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Syntheses and functions of heterometallic metallomacrocycles and coordination polymers"}]},"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"4","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2016)"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要（和文）：前駆Ir(III)-ヒドリド錯体と4-(2-ピリジル)ピリミジン(pprd)，6,6'-ジメチル-4,4'-ビピリミジン(Me2bpm)および4,4'-ビキナゾリン(biqz)を反応させ，配位不飽和サイトを有する5つの錯体配位子Ir(III)-{pprd, Me2bpm, biqz}/H2/PPh3 (1～5)を合成した。続いて，これらIr(III)-ヒドリド錯体配位子とAgCF3COOを反応させ，3つの新規なヘテロ金属Ag(I)-Ir(III)ヒドリド配位高分子Ir(III)-Ag(I)-{pprd, Me2bpm,biqz}/H2/PPh3/CF3COO (6～8)を構築した。\n研究成果の概要（英文）：A new type of Ir(III) metalloligands containing an unsaturated nitrogen coordination site, [Ir(H)2(PPh3)2(pprd)]BF4 (1), [Ir(H)2(PPh3)2(Me2bpm)]BF4 (2), {[Ir(H)2(PPh3)2(Me2bpm)]PF6}4 (3), [Ir(H)2(PPh3)2(biqz)]BF4 (4) and [Ir(H)2(PPh3)2(biqz)]PF6 (5), have been prepared by the reactions of [Ir(H)2(PPh3)2(Me2CO)2]X (X = BF4 and PF6) with 4-(2-pyridyl)pyrimidine (pprd), 6,6'-dimethyl-4,4'-bipyrimidine (Me2bpm) and 4,4'-biquinazoline (biqz). Subsequently, three novel heterometallic Ag(I)-Ir(III) hydride coordination polymers, {[Ir(H)2(μ-pprd)(PPh3)2Ag(η-CF3COO)]BF4 }n (6), {[Ir(H)2(μ-biqz)(PPh3)2Ag2(μ-CF3COO)3] }n (7) and {[Ir(H)2(μ-Me2bpm)(PPh3)2Ag2(μ-CF3COO)2]PF6}n (8) have been reasonably constructed by the reactions of Ir(III) metalloligands 1, 3 and 5 with AgCF3COO.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：基盤研究(C);  研究期間：2014～2016;   課題番号：26410079;   研究分野：化学;   科研費の分科・細目：","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-26410079/"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"MAEKAWA, MASAHIKO"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学理工学総合研究所; 教授"}]},"item_8_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"Kindai University"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_be7fb7dd8ff6fe43","subitem_version_type":"NA"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"前川, 雅彦"},{"creatorName":"マエカワ, マサヒコ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-11-01"}],"displaytype":"detail","filename":"26410079seika.pdf","filesize":[{"value":"320.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"26410079seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/18821/files/26410079seika.pdf"},"version_id":"abbd4a6a-fd11-46d2-91cf-f24f5bfcf453"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"イリジウム錯体","subitem_subject_scheme":"Other"},{"subitem_subject":"ヒドリド錯体","subitem_subject_scheme":"Other"},{"subitem_subject":"銀錯体","subitem_subject_scheme":"Other"},{"subitem_subject":"異種金属錯体","subitem_subject_scheme":"Other"},{"subitem_subject":"配位高分子","subitem_subject_scheme":"Other"},{"subitem_subject":"X線構造解析","subitem_subject_scheme":"Other"},{"subitem_subject":"NMR","subitem_subject_scheme":"Other"},{"subitem_subject":"多座窒素配位子","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"ヘテロ金属メタラマクロサイクリック・配位高分子の構築と機能","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ヘテロ金属メタラマクロサイクリック・配位高分子の構築と機能"}]},"item_type_id":"8","owner":"3","path":["4374"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-11-01"},"publish_date":"2017-11-01","publish_status":"0","recid":"18821","relation_version_is_last":true,"title":["ヘテロ金属メタラマクロサイクリック・配位高分子の構築と機能"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T21:48:56.238096+00:00"}