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Synthesis and Crystal Structure of Bis(diphenylphosphino)methane Dipalladium(I) Complex with 2-Vinylpyridine (vpy). [Pd_2(μ-dppm)_2(vpy)Cl]ClO_4
https://kindai.repo.nii.ac.jp/records/11291
https://kindai.repo.nii.ac.jp/records/11291c5cde600-edc0-4811-b835-125e4405a787
名前 / ファイル | ライセンス | アクション |
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AN10074306-19970305-0045.pdf (369.0 kB)
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Item type | ☆紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2015-04-03 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Synthesis and Crystal Structure of Bis(diphenylphosphino)methane Dipalladium(I) Complex with 2-Vinylpyridine (vpy). [Pd_2(μ-dppm)_2(vpy)Cl]ClO_4 | |||||
著者 |
Maekawa, Masahiko
× Maekawa, Masahiko× Munakata, Megumu× Kuroda-Sowa, Takayoshi× Suenaga, Yusaku |
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言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | palladium complexes, bis(diphenylphosphino)methane, 2-vinylpyridine, crystal structures, metal-metal bond | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
著者(英) | ||||||
en | ||||||
Maekawa, Masahiko | ||||||
著者(英) | ||||||
en | ||||||
Munakata, Megumu | ||||||
著者(英) | ||||||
en | ||||||
Kuroda-Sowa, Takayoshi | ||||||
著者(英) | ||||||
en | ||||||
Suenaga, Yusaku | ||||||
著者 所属 | ||||||
Research Institute for Science and Technology, Kinki University | ||||||
著者 所属 | ||||||
Department of Chemistry, Kinki University | ||||||
著者 所属 | ||||||
Department of Chemistry, Kinki University | ||||||
著者 所属 | ||||||
Department of Chemistry, Kinki University | ||||||
著者所属(翻訳) | ||||||
近畿大学理工学総合研究所 | ||||||
著者所属(翻訳) | ||||||
近畿大学 | ||||||
著者所属(翻訳) | ||||||
近畿大学 | ||||||
著者所属(翻訳) | ||||||
近畿大学 | ||||||
版 | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 名前 | ||||||
出版者 | 近畿大学理工学総合研究所 | |||||
書誌情報 |
理工学総合研究所研究報告 en : Annual reports by Research Institute for Science and Technology 巻 9, p. 45-51, 発行日 1997-03-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 09162054 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | [Abstract] The bis(diphenylphosphino)methane dipalladium(I) complex: with 2-vinylpyridine, [Pd_2(μ-dppm)_2(vpy)Cl]ClO_4 (1) has been prepared and characterized crystallographically. Two Pd atoms are doubly bridged by two dppm ligands to form an eight-membered Pd_2P_4C_2 ring framework in a twist-chair conformation. Each Pd atoms are also coordinated by Cl^- ion and N atom of vpy ligand to provide a side-by-side conformation. The Pd-Pd distance of 2.597(2)Å is rather shorter than that (2.75Å) in the Pd metal, indicative of the existence of a direct Pd-Pd bond. On the eight-membered Pd_2C_2P_4 ring, the torsion angle of 43.2° is close to 45° and the Pd-Pd bond of 2.597(2)Å is also shorter than those in other dipalladium(I) dppm complexes. It has been experimentally found that the closer torsion angle is to 45°, the shorter Pd-Pd distance is. Complex 1 has the following crystal data: orthorhombic, P2_12_12_1, a=11.882(5), 6=11.909(7), c=38.676(5)Å, F=5473(3)Å^3, Z=4, R=0.048 and R_w=0.046. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |