WEKO3
アイテム
{"_buckets": {"deposit": "45a062fb-e469-42a6-89b6-b892a4042686"}, "_deposit": {"created_by": 3, "id": "11144", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "11144"}, "status": "published"}, "_oai": {"id": "oai:kindai.repo.nii.ac.jp:00011144", "sets": ["2101"]}, "author_link": ["21459", "21461", "21463", "21460", "21462"], "item_2_biblio_info_21": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2011-02-01", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "23", "bibliographicPageEnd": "33", "bibliographicPageStart": "23", "bibliographic_titles": [{"bibliographic_title": "理工学総合研究所研究報告"}, {"bibliographic_title": "Annual reports by Research Institute for Science and Technology", "bibliographic_titleLang": "en"}]}]}, "item_2_date_19": {"attribute_name": "日付 作成日", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2011-05-12", "subitem_date_issued_type": "Created"}]}, "item_2_description_33": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "[Abstract] Three bis(catechol) compounds 5,5\u0027-(buta-1,3-diyne-1,4-diyl) bis(3-tert-butylcatechol) (Biscat 1), 5,5\u0027-(2,5-dimethoxy-1,4-phenylene)bis(ethyne-2,1-diyl)bis(3-tert-butyl-catechol) (Biscat 2) and 5,5\u0027-(1,3-phenylene)bis(ethyne-2,1-diyl)bis(3-tert-butylcatechol) (Biscat 3) were obtained from cross-coupling reactions. Biscat 1 and Biscat 2 were characterized by X-ray crystal analysis and cyclic voltammetry (CV). The results from Xray crystal analysis shows that Biscat 1 and 2 possess a rod like structure with molecular lengths 14.7Å for Biscat 1 and 19.3Å for Biscat 2. In Biscat 1, the two catechol rings are not in the same plane and the dihedral angle of terminal catechol rings is about 25°. CVs for Biscat 1 and 2 were measured under alkaline conditions. An oxidation wave was observed corresponding to Sq-Sq (Sq: semiquinone)→Bq-Bq (Bq: benzoquinone) at around -300 mV. However, the redox waves disappeared when the CV scan was repeated. In contrast, Biscat 3 showed stable redox waves in the range from -1 V to +1.5 V even in alkaline conditions. These results suggest that Biscat 1 and 2 were converted into polymer or oligomer compounds (insoluble materials) through the Bq-Bq structures during repeat of the CV scans.", "subitem_description_type": "Abstract"}]}, "item_2_description_37": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"subitem_description": "Departmental Bulletin Paper", "subitem_description_type": "Other"}]}, "item_2_description_41": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_2_publisher_14": {"attribute_name": "出版者 名前", "attribute_value_mlt": [{"subitem_publisher": "近畿大学理工学総合研究所"}]}, "item_2_source_id_22": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "09162054", "subitem_source_identifier_type": "ISSN"}]}, "item_2_text_15": {"attribute_name": "出版社 カナ", "attribute_value_mlt": [{"subitem_text_value": "キンキ ダイガク リコウガク ソウゴウ ケンキュウジョ"}]}, "item_2_text_16": {"attribute_name": "出版社 ローマ字", "attribute_value_mlt": [{"subitem_text_value": "Kinki daigaku rikogaku sogo kenkyusho"}]}, "item_2_text_17": {"attribute_name": "出版年(from)", "attribute_value_mlt": [{"subitem_text_value": "2011"}]}, "item_2_text_18": {"attribute_name": "出版年(to)", "attribute_value_mlt": [{"subitem_text_value": "02-28"}]}, "item_2_text_44": {"attribute_name": "ID(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "AN10074306-20110228-0023"}]}, "item_2_text_47": {"attribute_name": "日付 記録日(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "2011-05-12"}]}, "item_2_text_51": {"attribute_name": "最終更新日(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "May 14, 2011 09:00:00"}]}, "item_2_text_53": {"attribute_name": "登録者(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "kurepo"}]}, "item_2_text_54": {"attribute_name": "閲覧数(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "68"}]}, "item_2_text_55": {"attribute_name": "ダウンロード数(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "130"}]}, "item_2_text_56": {"attribute_name": "XooNIps_ITEM_KEY", "attribute_value_mlt": [{"subitem_text_value": "9492"}]}, "item_2_text_7": {"attribute_name": "著者(英)", "attribute_value_mlt": [{"subitem_text_language": "en", "subitem_text_value": "\u0026EMPTY\u0026"}, {"subitem_text_language": "en", "subitem_text_value": "\u0026EMPTY\u0026"}, {"subitem_text_language": "en", "subitem_text_value": "\u0026EMPTY\u0026"}, {"subitem_text_language": "en", "subitem_text_value": "\u0026EMPTY\u0026"}, {"subitem_text_language": "en", "subitem_text_value": "前川, 雅彦"}]}, "item_2_text_8": {"attribute_name": "著者 所属", "attribute_value_mlt": [{"subitem_text_value": "Department of Chemistry, Kinki University:Research Institute for Science and Technology, Kinki University"}, {"subitem_text_value": "Department of Chemistry, Kinki University"}, {"subitem_text_value": "Department of Chemistry, Kinki University"}, {"subitem_text_value": "Department of Chemistry, Kinki University"}, {"subitem_text_value": "Research Institute for Science and Technology, Kinki University"}]}, "item_2_version_type_12": {"attribute_name": "版", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Suenaga, Yusaku"}, {"creatorName": "スエナガ, ユウサク", "creatorNameLang": "ja-Kana"}], "nameIdentifiers": [{"nameIdentifier": "21459", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hirano, Yasuhiro"}, {"creatorName": "ヒラノ, ヤスヒロ", "creatorNameLang": "ja-Kana"}], "nameIdentifiers": [{"nameIdentifier": "21460", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Umehata, Yukiko"}, {"creatorName": "ウメハタ, ユキコ", "creatorNameLang": "ja-Kana"}], "nameIdentifiers": [{"nameIdentifier": "21461", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kamei, Kuniaki"}, {"creatorName": "カメイ, クニアキ", "creatorNameLang": "ja-Kana"}], "nameIdentifiers": [{"nameIdentifier": "21462", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Maekawa, Masahiko"}, {"creatorName": "マエカワ, マサヒコ", "creatorNameLang": "ja-Kana"}], "nameIdentifiers": [{"nameIdentifier": "21463", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-02-19"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "AN10074306-20110228-0023.pdf", "filesize": [{"value": "4.7 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 4700000.0, "url": {"label": "AN10074306-20110228-0023.pdf", "url": "https://kindai.repo.nii.ac.jp/record/11144/files/AN10074306-20110228-0023.pdf"}, "version_id": "d390bfe9-a381-4f66-8289-d102a39612b9"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "bis(catechol)", "subitem_subject_scheme": "Other"}, {"subitem_subject": "acetylene group", "subitem_subject_scheme": "Other"}, {"subitem_subject": "rod like structure", "subitem_subject_scheme": "Other"}, {"subitem_subject": "electrochemical behavior", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Syntheses, crystal structures and electrochemical properties of bis(catechol)s with acetylene group", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Syntheses, crystal structures and electrochemical properties of bis(catechol)s with acetylene group", "subitem_title_language": "en"}]}, "item_type_id": "2", "owner": "3", "path": ["2101", "3567"], "permalink_uri": "https://kindai.repo.nii.ac.jp/records/11144", "pubdate": {"attribute_name": "公開日", "attribute_value": "2011-05-14"}, "publish_date": "2011-05-14", "publish_status": "0", "recid": "11144", "relation": {}, "relation_version_is_last": true, "title": ["Syntheses, crystal structures and electrochemical properties of bis(catechol)s with acetylene group"], "weko_shared_id": 3}
Syntheses, crystal structures and electrochemical properties of bis(catechol)s with acetylene group
https://kindai.repo.nii.ac.jp/records/11144
https://kindai.repo.nii.ac.jp/records/1114483ddf827-0a92-4b35-b3c0-25b96196cf28
名前 / ファイル | ライセンス | アクション |
---|---|---|
AN10074306-20110228-0023.pdf (4.7 MB)
|
|
Item type | ☆紀要論文 / Departmental Bulletin Paper(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2011-05-14 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Syntheses, crystal structures and electrochemical properties of bis(catechol)s with acetylene group | |||||
著者 |
Suenaga, Yusaku
× Suenaga, Yusaku× Hirano, Yasuhiro× Umehata, Yukiko× Kamei, Kuniaki× Maekawa, Masahiko |
|||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | bis(catechol), acetylene group, rod like structure, electrochemical behavior | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
著者(英) | ||||||
en | ||||||
著者(英) | ||||||
en | ||||||
著者(英) | ||||||
en | ||||||
著者(英) | ||||||
en | ||||||
著者(英) | ||||||
en | ||||||
前川, 雅彦 | ||||||
著者 所属 | ||||||
Department of Chemistry, Kinki University:Research Institute for Science and Technology, Kinki University | ||||||
著者 所属 | ||||||
Department of Chemistry, Kinki University | ||||||
著者 所属 | ||||||
Department of Chemistry, Kinki University | ||||||
著者 所属 | ||||||
Department of Chemistry, Kinki University | ||||||
著者 所属 | ||||||
Research Institute for Science and Technology, Kinki University | ||||||
版 | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 名前 | ||||||
出版者 | 近畿大学理工学総合研究所 | |||||
書誌情報 |
理工学総合研究所研究報告 en : Annual reports by Research Institute for Science and Technology 号 23, p. 23-33, 発行日 2011-02-01 |
|||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 09162054 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | [Abstract] Three bis(catechol) compounds 5,5'-(buta-1,3-diyne-1,4-diyl) bis(3-tert-butylcatechol) (Biscat 1), 5,5'-(2,5-dimethoxy-1,4-phenylene)bis(ethyne-2,1-diyl)bis(3-tert-butyl-catechol) (Biscat 2) and 5,5'-(1,3-phenylene)bis(ethyne-2,1-diyl)bis(3-tert-butylcatechol) (Biscat 3) were obtained from cross-coupling reactions. Biscat 1 and Biscat 2 were characterized by X-ray crystal analysis and cyclic voltammetry (CV). The results from Xray crystal analysis shows that Biscat 1 and 2 possess a rod like structure with molecular lengths 14.7Å for Biscat 1 and 19.3Å for Biscat 2. In Biscat 1, the two catechol rings are not in the same plane and the dihedral angle of terminal catechol rings is about 25°. CVs for Biscat 1 and 2 were measured under alkaline conditions. An oxidation wave was observed corresponding to Sq-Sq (Sq: semiquinone)→Bq-Bq (Bq: benzoquinone) at around -300 mV. However, the redox waves disappeared when the CV scan was repeated. In contrast, Biscat 3 showed stable redox waves in the range from -1 V to +1.5 V even in alkaline conditions. These results suggest that Biscat 1 and 2 were converted into polymer or oligomer compounds (insoluble materials) through the Bq-Bq structures during repeat of the CV scans. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |