{"created":"2023-06-20T16:37:31.685619+00:00","id":7301,"links":{},"metadata":{"_buckets":{"deposit":"56333a96-c14a-4b79-8729-f07fb01b521a"},"_deposit":{"created_by":3,"id":"7301","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"7301"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00007301","sets":["14:923:1711:1721","21:3039:3241:3285"]},"author_link":["12490","12493","12491","12492"],"item_2_alternative_title_3":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"<Original Papers>Preparation of Fluorinated Polyurethanes Having an Antifouling Ability"}]},"item_2_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-12-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"44","bibliographicPageEnd":"13","bibliographicPageStart":"9","bibliographic_titles":[{"bibliographic_title":"近畿大学工学部研究報告"},{"bibliographic_title":"Research reports of the Faculty of Engineering, Kinki University","bibliographic_titleLang":"en"}]}]},"item_2_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"[Abstract]With the aim of preparing the novel antifouling paint, polyurethanes including fluoro-substituted methyl- or methylene groups in the main chain were obtained from a typical surface polyaddition of fluoro-substituted bisphenol A and various diols to diisocyanates using tetrabutylammonium bromide (TBAB) as a phase transfer catalyst . Fluoro-substituted compounds used were 2,2-bis(4-hydroxyphenyl) hexafluoropropane (BHPHFP) , 2,2,3,3-tetrafuluoro-1,4-butanediol(TFBDO) , 2,2,3,3,4,4- hexafluoro-1,5-pentanediol (HFPDO) and 2,2,3,3,4,4,5,5,6,6,7,7- dodecafluoro-1,8-octanediol (DFODO), whereas diisocyanates used were phenylene-1,4- diisocyanate (1,4-PDI), tolylene-2,4-diisocyanate (2,4-TDI) and tolylene -2,6-diisocyanate (2,6-TDI). Polyaddition with a molar ratio of 0.5 : 0.5 for the diol in NaOH aqueous solution and diisocyanate in carbon tetrachloride gave the twelve kinds of fluorinated polyurethanes . From the solubility test to some organic solvents, polyurethanes consisting of aliphatic diol dissolve in dimethyl sulfoxide, dimethyl formamide and tetrahydrofuran. The measurements of contact angle to water and colza oil confirmed that the introduction of fluorine atoms into polyurethane results in preventing from the air pollution.","subitem_description_type":"Abstract"}]},"item_2_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学工学部"}]},"item_2_source_id_22":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0386491X","subitem_source_identifier_type":"ISSN"}]},"item_2_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"KAWAKAMI, Tatsuya"},{"subitem_text_language":"en","subitem_text_value":"SHIRAISHI, Kohei"},{"subitem_text_language":"en","subitem_text_value":"HISANAGA, Naokatsu"},{"subitem_text_language":"en","subitem_text_value":"SUGIYAMA, Kazuo"}]},"item_2_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学大学院システム工学研究科"},{"subitem_text_value":"近畿大学工学部生物化学工学科:近畿大学大学院システム工学研究科"},{"subitem_text_value":"サンユレック株式会社"},{"subitem_text_value":"近畿大学工学部生物化学工学科:近畿大学大学院システム工学研究科"}]},"item_2_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"Graduate School of Systems Engineering, Kinki University"},{"subitem_text_value":"Graduate School of Systems Engineering, Kinki University"},{"subitem_text_value":"SANYU REC Co. Ltd"},{"subitem_text_value":"Graduate School of Systems Engineering, Kinki University"}]},"item_2_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"川上,  達也"},{"creatorName":"カワカミ, タツヤ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"白石,  浩平"},{"creatorName":"シライシ, コウヘイ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"久永,  直克"},{"creatorName":"ヒサナガ, ナオカツ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"杉山,  一男"},{"creatorName":"スギヤマ, カズオ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-18"}],"displaytype":"detail","filename":"AN00063799-20101220-0009.pdf","filesize":[{"value":"3.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"AN00063799-20101220-0009.pdf","url":"https://kindai.repo.nii.ac.jp/record/7301/files/AN00063799-20101220-0009.pdf"},"version_id":"621e877a-c065-4fe3-a4f7-a4f3fd1d53e2"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Antifouling Ability","subitem_subject_scheme":"Other"},{"subitem_subject":"Fluorinated Polyurethanes","subitem_subject_scheme":"Other"},{"subitem_subject":"Fluorinated Diols","subitem_subject_scheme":"Other"},{"subitem_subject":"Aromatic Diisocyanates","subitem_subject_scheme":"Other"},{"subitem_subject":"Surface polyaddition","subitem_subject_scheme":"Other"},{"subitem_subject":"Phase Transfer Catalyst","subitem_subject_scheme":"Other"},{"subitem_subject":"Contact Angle","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"<研究論文>防汚機能をもつ含フッ素ポリウレタンコーティング剤の調製","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"<研究論文>防汚機能をもつ含フッ素ポリウレタンコーティング剤の調製"}]},"item_type_id":"2","owner":"3","path":["1721","3285"],"pubdate":{"attribute_name":"公開日","attribute_value":"2011-02-21"},"publish_date":"2011-02-21","publish_status":"0","recid":"7301","relation_version_is_last":true,"title":["<研究論文>防汚機能をもつ含フッ素ポリウレタンコーティング剤の調製"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-06-21T00:19:00.648181+00:00"}