{"created":"2023-06-20T16:35:33.090819+00:00","id":4908,"links":{},"metadata":{"_buckets":{"deposit":"cd0cc8e8-2e83-4c0a-a83e-071694b93d5f"},"_deposit":{"created_by":3,"id":"4908","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"4908"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00004908","sets":["14:923:1379:1419","21:3039:3040:3052"]},"author_link":["6707","6703","6704","6706","6702","6705"],"item_2_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1996-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"29","bibliographicPageEnd":"62","bibliographicPageStart":"53","bibliographic_titles":[{"bibliographic_title":"近畿大学農学部紀要"},{"bibliographic_title":"Memoirs of the Faculty of Agriculture of Kinki University","bibliographic_titleLang":"en"}]}]},"item_2_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"[Author Abstract]As a fundamental study searching for useful nonlinear optical material of secondary harmonic generation (SHG), the efficiency of regulation of parallel molecular arrangement by a steroidal subunit was examined by constructing a molecule having a large steroidal subunit attached with a conjugated π-electron system of substituted benzylidene group which contributes to generation of SHG. Starting from the three steroids shown in the title and 15 substituted benzaldehydes, 45 substituted benzylidenesteroid compounds were prepared and their physical properties were measured. This paper reports the syntheses and some properties such as electronic spectra and melting points of the products. [著者抄録]近年急速に発展した光エレクトロニクスの分野では,レーザー波長を自由に変換できる素子として非線形光学材料が注目を集め,中でもレーザー波長を1/2に変換する第2高調波発生(SHG)に期待がよせられている。大きなSHGを持つ材料は,大きな2次非線形分子分極率(β)を待つ分子が同一方向に並ぶ時得られる。本研究は,ステロイド系天然物のもつ非対称構造を分子配列の制御に利用するSHG材料開発の可能性について,表題の三種のステロイドと15種のベンズアルデヒドとから45種の置換ベンジリデンステロイドを合成して検討を行なった。本報告は合成と物性の一部を報告する。","subitem_description_type":"Abstract"}]},"item_2_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"記事区分：原著","subitem_description_type":"Other"}]},"item_2_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学農学部"}]},"item_2_source_id_22":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"04538889","subitem_source_identifier_type":"ISSN"}]},"item_2_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Sano, Seiji"},{"subitem_text_language":"en","subitem_text_value":"Inoue, Yuji"},{"subitem_text_language":"en","subitem_text_value":"Ishigaki, Kenichi"},{"subitem_text_language":"en","subitem_text_value":"Takatani, Masahiro"},{"subitem_text_language":"en","subitem_text_value":"Kaji, Makoto"},{"subitem_text_language":"en","subitem_text_value":"Okamoto, Tadashi"}]},"item_2_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学大学院農学研究科林産利用学研究室"},{"subitem_text_value":"近畿大学農学部農芸科学科天然高分子化学研究室"},{"subitem_text_value":"近畿大学農学部農芸科学科天然高分子化学研究室"},{"subitem_text_value":"近畿大学農学部農芸科学科天然高分子化学研究室"},{"subitem_text_value":"日立化成工業株式会社茨城研究所"},{"subitem_text_value":"近畿大学農学部農芸科学科天然高分子化学研究室"}]},"item_2_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"Laboratory of Wood Products, Graduate School of Agriculture, Kinki University"},{"subitem_text_value":"Laboratory of Natural High-Polymer Chemistry, Department of Agricultural Chemistry, Faculty of Agriculture, Kinki University"},{"subitem_text_value":"Laboratory of Natural High-Polymer Chemistry, Department of Agricultural Chemistry, Faculty of Agriculture, Kinki University"},{"subitem_text_value":"Laboratory of Natural High-Polymer Chemistry, Department of Agricultural Chemistry, Faculty of Agriculture, Kinki University"},{"subitem_text_value":"Ibaraki Research Lab., Hitachi Chem. Ind. Co. LTD."},{"subitem_text_value":"Laboratory of Natural High-Polymer Chemistry, Department of Agricultural Chemistry, Faculty of Agriculture, Kinki University"}]},"item_2_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_be7fb7dd8ff6fe43","subitem_version_type":"NA"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"佐野,  誠二"},{"creatorName":"サノ, セイジ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"井上,  裕二"},{"creatorName":"イノウエ, ユウジ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"石垣,  健一"},{"creatorName":"イシガキ, ケンイチ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"高谷,  正弘"},{"creatorName":"タカタニ, マサヒロ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"鍛冶,  誠"},{"creatorName":"カジ, マコト","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"岡本,  忠"},{"creatorName":"オカモト, タダシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-18"}],"displaytype":"detail","filename":"AN00064044-19960315-0053.pdf","filesize":[{"value":"1.1 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"AN00064044-19960315-0053.pdf","url":"https://kindai.repo.nii.ac.jp/record/4908/files/AN00064044-19960315-0053.pdf"},"version_id":"f5d3b594-2415-49bb-89d6-82f6a385d013"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_thumbnail":{"attribute_name":"サムネイル","attribute_value_mlt":[{"subitem_thumbnail":[{"thumbnail_label":"AN00064044-19960315-0053.jpeg","thumbnail_url":"/api/files/cd0cc8e8-2e83-4c0a-a83e-071694b93d5f/AN00064044-19960315-0053.jpeg?versionId=762fd91d-6876-4661-974b-f01bc3da2a5a"}]}]},"item_title":"ステロイドを原料とするSHG物質 (I) : エストロンメチルエーテル，デヒドロエピアンドロステロン，アンドロスタジエンジオンの4-置換ベンジリデン誘導体の合成とその性質","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ステロイドを原料とするSHG物質 (I) : エストロンメチルエーテル，デヒドロエピアンドロステロン，アンドロスタジエンジオンの4-置換ベンジリデン誘導体の合成とその性質"},{"subitem_title":"Steroid-Based SHG Material. I. : Preparation and Some Physical Properties of 4-Substituted-Benzylidene Derivatives of Estrone Methyl Ether, Dehydroepiandrosterone, and Androsta-1,4-dine-3,17-dione","subitem_title_language":"en"}]},"item_type_id":"2","owner":"3","path":["1419","3052"],"pubdate":{"attribute_name":"公開日","attribute_value":"2008-01-28"},"publish_date":"2008-01-28","publish_status":"0","recid":"4908","relation_version_is_last":true,"title":["ステロイドを原料とするSHG物質 (I) : エストロンメチルエーテル，デヒドロエピアンドロステロン，アンドロスタジエンジオンの4-置換ベンジリデン誘導体の合成とその性質"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T19:29:18.827175+00:00"}