{"created":"2023-06-20T16:34:19.097174+00:00","id":3482,"links":{},"metadata":{"_buckets":{"deposit":"814c2f47-cdff-4158-b9da-0c441aa8676c"},"_deposit":{"created_by":3,"id":"3482","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3482"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00003482","sets":["14:2667:2668:2987","21:2669:2670:2988"]},"author_link":["4140"],"item_8_alternative_title_3":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Fine Band Engineering of TiO2 by the Surface Modification with Moelcular Scale Metal Oxide Clusters"}]},"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-01-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"5","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2014 )"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要（和文): 本研究では, 第一遷移金属酸化物ナノクラスター表面修飾Ti02(MOs/Ti02)を調製し, その熱および光触媒活性を系統的に調べると共に活性支配因子を解明した. また, MOs/Ti02の中でも, Co203/Ti02は, Ti02のUV光活性を維持しつつ高い可視光活性(300 < 波長 < 800nm)を発現すると同時に触媒活性(波長 > 800 nm)を合わせ持つことを見出し, これが理想的な\"ソーラー環境触媒\"になりうることを示した. 平成24年度～平成26年度までの研究成果をまとめてレビューとして公表した(J. Phys. Chem. C 2014, 118, 12077-12086).                    研究成果の概要（英文): Molecular scale oxides of 3d metals were formed on Ti02 with the loading amountprecisely controlled by using the CCC technique (MOs/Ti02). The photocatalytic activity of MOs/Ti02 for the degradation of organic pollutants was systematically studied. Among them, Co203, Fe203 and NiO/Ti02 exhibit a high level of visible-light activity (400 < wavelength < 800 nm) with the UV-light activity of Ti02 maintained (wavelength < 400 nm). Co203 /Ti02 also has a thermocatalytic activity (wavelength > 800 nm), and it can be a promising \"solar environmental catalyst\" effectively utilizing the sunlight as an energy source. Further, we clarified the factors for affecting photocatalytic and thermocatalytic activities on the basis of experimental and DFT calculation results.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：基盤研究(C);  研究期間：2012～2014;   課題番号：24550239;   研究分野：無機物理化学;   科研費の分科・細目：","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/d/r/60298990.ja.html"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"TADA, Hiroaki"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学理工学部; 教授"}]},"item_8_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"Kinki University"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"多田,  弘明"},{"creatorName":"タダ, ヒロアキ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-17"}],"displaytype":"detail","filename":"24550239seika.pdf","filesize":[{"value":"172.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"24550239seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/3482/files/24550239seika.pdf"},"version_id":"f170b978-6c97-42a1-89ac-d7146dbb5971"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"光触媒","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"金属酸化物表面修飾による酸化チタンバンドエネルギー微調節および強吸着サイトの創出","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"金属酸化物表面修飾による酸化チタンバンドエネルギー微調節および強吸着サイトの創出"}]},"item_type_id":"8","owner":"3","path":["2987","2988"],"pubdate":{"attribute_name":"公開日","attribute_value":"2015-11-18"},"publish_date":"2015-11-18","publish_status":"0","recid":"3482","relation_version_is_last":true,"title":["金属酸化物表面修飾による酸化チタンバンドエネルギー微調節および強吸着サイトの創出"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-06-21T01:34:04.053776+00:00"}