{"created":"2023-06-20T16:34:19.038947+00:00","id":3481,"links":{},"metadata":{"_buckets":{"deposit":"95b79954-b272-4eda-81e2-bfafd95986b1"},"_deposit":{"created_by":3,"id":"3481","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3481"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00003481","sets":["14:2667:2668:2987","21:2669:2670:2988"]},"author_link":["4138","4139"],"item_8_alternative_title_3":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Nonclassical control of chiral optical properties in chiral supramolecular organic fluorophore"}]},"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-01-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"6","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2014 )"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要（和文): 機能の異なる2種類の機能性分子（発光性分子と光学活性分子あるいは光学活性有機発光体とマトリックス）を組み合わせることにより, 円偏光発光(CPL)特性を有する光学活性ハイブリッド超分子有機発光体の開発に成功した. さらに, 同じ軸性キラリティーを有する光学活性ビナフチル有機発光体において, 光学活性ビナフチルの二面体角の角度の違い, 光学活性ビナフチルユニットの永久双極子モーメントの方向の違い, さらには外部マトリックスの違いにより, CPLの回転方向の制御に成功した.                      研究成果の概要（英文): Chiral hybride supramolecular organic fluorophore was successfully prepared by using two functional component molecules (fluorescent and chiral molecules or chiral fluorescent and matrix molecules). Intersetingly, it was found that the chiroptical signs of chiral binaphthyl organic fluorophores with the same axial chirality are controllable: (i) by controlling the dihedral angle of the binaphthyl units; (ii) by employing the neighbouring effect between the fluorescent binaphthyl units, and (iii) by manipulating their external environments, in addition to using opposite chiral counterparts.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：基盤研究(C);  研究期間：2012～2014;   課題番号：24550165;   研究分野：化学;   科研費の分科・細目：","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/d/r/80388496.ja.html"}]},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/d/r/90186552.ja.html"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"},{"subitem_text_value":"連携研究者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"IMAI, Yoshitane"},{"subitem_text_language":"en","subitem_text_value":"KURODA, Reiko"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学理工学部; 准教授"},{"subitem_text_value":"東京理科大学総合研究機構; 教授"}]},"item_8_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"Kinki University"},{"subitem_text_value":"Tokyo University of Science"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"今井,  喜胤"},{"creatorName":"イマイ, ヨシタネ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"黒田,  玲子"},{"creatorName":"クロダ, レイコ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-17"}],"displaytype":"detail","filename":"24550165seika.pdf","filesize":[{"value":"876.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"24550165seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/3481/files/24550165seika.pdf"},"version_id":"967b5185-1772-4624-9344-966b297ff929"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"円偏光発光","subitem_subject_scheme":"Other"},{"subitem_subject":"円偏光二色性","subitem_subject_scheme":"Other"},{"subitem_subject":"CPL","subitem_subject_scheme":"Other"},{"subitem_subject":"蛍光","subitem_subject_scheme":"Other"},{"subitem_subject":"超分子","subitem_subject_scheme":"Other"},{"subitem_subject":"キラル","subitem_subject_scheme":"Other"},{"subitem_subject":"光学活性","subitem_subject_scheme":"Other"},{"subitem_subject":"ビナフチル","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"非古典的手法を用いた光学活性超分子有機発光体のキラルな光学特性制御","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"非古典的手法を用いた光学活性超分子有機発光体のキラルな光学特性制御"}]},"item_type_id":"8","owner":"3","path":["2987","2988"],"pubdate":{"attribute_name":"公開日","attribute_value":"2015-11-18"},"publish_date":"2015-11-18","publish_status":"0","recid":"3481","relation_version_is_last":true,"title":["非古典的手法を用いた光学活性超分子有機発光体のキラルな光学特性制御"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-06-21T01:34:06.225255+00:00"}