{"created":"2023-06-20T16:34:06.017864+00:00","id":3184,"links":{},"metadata":{"_buckets":{"deposit":"f321aeb2-551c-4fbf-b78e-c13c57ec1801"},"_deposit":{"created_by":3,"id":"3184","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3184"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00003184","sets":["14:2667:2685:2686","21:2669:2687:2688"]},"author_link":["3600","3601","3599","3598"],"item_8_alternative_title_3":{"attribute_name":"その他(別言語等)のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Synthesis and Application of New Functional Polymers Utilizing Redox System of Vicinal Tricarbonyl Structure"}]},"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2011-01-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"5","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費補助金研究成果報告書 (2011. )"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要(和文):隣接トリカルボニル基を側鎖にもつポリスチレン誘導体を設計・合成した。そのRedox特性を利用した反応を検討する過程において、隣接トリカルボニル基に水やモノアルコールが無触媒下、室温で付加することを見いだした。この付加反応は可逆的であり、これらの付加体を減圧下で加熱すると元の隣接トリカルボニルポリマーが定量的に回収できることもわかった。同様にジオールを用いるとアルコール付加体部位が架橋点となり、各種溶媒に不溶のネットワークポリマーが生成した。一方、このネットワークポリマーをDMSO/H20(9/1,v/v)中で撹拝した後、減圧下で加熱して揮発性分を留去することにより、元の隣接トリカルボニルポリマーをほぼ定量的に回収した。 研究成果の概要(英文):We designed and synthesized new polystyrene derivatives bearing vicinal tricarbonyl group in the side chain. Over the course of our study to investigate the reactions utilizing the redox properties of the vicinal tricarbonyl structures, we found that water and monoalcohols added to their vicinal tricarbonyl groups at ambient temperature without any catalyst. The addition was reversible and the original vicinal tricarbonyl polymer was recovered by heating under reduced pressure. Similarly, diols reacted with the vicinal tricarbonyl groups to give networked polymer that are insoluble to most common solvents as a result of the newly formed alcohol adduct units acting as crosslinking points. On the other hand, the original vicinal tricarbonyl polymer was recovered by stirring in DMSO/H_2O(9 /1, v/v) followed by heating under reduced pressure so as to remove volatile components.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目:基盤研究(B); 研究期間:2009~2011; 課題番号:21350030; 研究分野:化学; 科研費の分科・細目:複合化学・高分子化学","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://kaken.nii.ac.jp/d/r/40016738.ja.html"}]},{"subitem_relation_name":[{"subitem_relation_name_text":"http://kaken.nii.ac.jp/d/r/20293053.ja.html"}]},{"subitem_relation_name":[{"subitem_relation_name_text":"http://kaken.nii.ac.jp/d/r/00362286.ja.html"}]},{"subitem_relation_name":[{"subitem_relation_name_text":"http://kaken.nii.ac.jp/d/r/00281270.ja.html"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"},{"subitem_text_value":"研究分担者"},{"subitem_text_value":"研究分担者"},{"subitem_text_value":"研究分担者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"ENDO, TAKESHI"},{"subitem_text_language":"en","subitem_text_value":"SUDO, ATSUSHI"},{"subitem_text_language":"en","subitem_text_value":"MORINO, KAZUHIDE"},{"subitem_text_language":"en","subitem_text_value":"HURUSHO, YOSHIO"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学分子工学研究所; 教授"},{"subitem_text_value":"近畿大学分子工学研究所; 准教授"},{"subitem_text_value":"近畿大学分子工学研究所; 講師"},{"subitem_text_value":"近畿大学分子工学研究所; 准教授"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"遠藤, 剛"},{"creatorName":"エンドウ, タケシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"須藤, 篤"},{"creatorName":"スドウ, アツシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"森野, 一英"},{"creatorName":"モリノ, カズヒデ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"古荘, 義雄"},{"creatorName":"フルショウ, ヨシオ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-17"}],"displaytype":"detail","filename":"KAKEN_21350068seika.pdf","filesize":[{"value":"1.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KAKEN_21350068seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/3184/files/KAKEN_21350068seika.pdf"},"version_id":"0f535f0c-8eba-4162-828a-158d3a02055a"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"機能性高分子","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"隣接トリカルボニル骨格のRedox系を利用した新規機能性高分子の創製と応用","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"隣接トリカルボニル骨格のRedox系を利用した新規機能性高分子の創製と応用"}]},"item_type_id":"8","owner":"3","path":["2686","2688"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-09-25"},"publish_date":"2012-09-25","publish_status":"0","recid":"3184","relation_version_is_last":true,"title":["隣接トリカルボニル骨格のRedox系を利用した新規機能性高分子の創製と応用"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-06-21T01:43:48.543411+00:00"}