{"created":"2023-06-20T16:34:03.811329+00:00","id":3147,"links":{},"metadata":{"_buckets":{"deposit":"d2e30a3c-2e3d-4a6a-b412-0a858594d41b"},"_deposit":{"created_by":3,"id":"3147","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3147"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00003147","sets":["14:2667:2689:2693","21:2669:2691:2694"]},"author_link":["3489","3488"],"item_8_alternative_title_3":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Development of effective method for an introduction of decarboxylative nucleophile in the synthesis of indole derivative and its application to solid phase catalytic reaction"}]},"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-01-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"4","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費補助金研究成果報告書 (2010. )"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要（和文）：インドール-2,3-ジカルボン酸に超原子価ヨウ素試薬およびハロゲン化リチウムを作用させると、脱炭酸的ハロゲン化が進行し、相当する2,3-ジハロインドールに変換できた。本結果を利用してピロロフェナンスリドンアルカロイドの合成に成功した。さらに4-メトキシ安息香酸から４-ヨードアニソールを収率良く与えた。      研究成果の概要（英文）：Reaction of indole-2,3-dicarboxylic acids with hypervalent iodine reagent and lithium halide gave the corresponding 2,3-dihaloindoles via decarboxylative halogenation. Pyrrolophenanthridone alkaloids were also synthesized via decarboxylative halogenation and reduction of the iodo compound. In a similar manner, 4-methoxybenzoic acid derivatives were also converted to 4-iodoanisoles.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：基盤研究（C）;  研究期間：2008～2011;   課題番号：20590024;   研究分野：有機化学;   科研費の分科・細目：薬学・化学系薬学","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/r/40122113"}]},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/r/40365896"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"},{"subitem_text_value":"研究分担者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"MIKI, YASUYOSHI"},{"subitem_text_language":"en","subitem_text_value":"HAMAMOTO, HIROMI"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学薬学部; 教授"},{"subitem_text_value":"近畿大学薬学部; 講師"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"三木,  康義"},{"creatorName":"ミキ, ヤスヨシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"濱本,  博三"},{"creatorName":"ハマモト, ヒロミ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-17"}],"displaytype":"detail","filename":"KAKEN_20590024seika.pdf","filesize":[{"value":"238.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KAKEN_20590024seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/3147/files/KAKEN_20590024seika.pdf"},"version_id":"92330fdc-4e59-4394-9c7a-6ef0acd44951"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"インドール関連化合物合成に有効な脱炭酸的求核種導入法の開発と固相触媒反応への応用","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"インドール関連化合物合成に有効な脱炭酸的求核種導入法の開発と固相触媒反応への応用"}]},"item_type_id":"8","owner":"3","path":["2693","2694"],"pubdate":{"attribute_name":"公開日","attribute_value":"2011-07-08"},"publish_date":"2011-07-08","publish_status":"0","recid":"3147","relation_version_is_last":true,"title":["インドール関連化合物合成に有効な脱炭酸的求核種導入法の開発と固相触媒反応への応用"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-06-21T01:45:08.562408+00:00"}