{"created":"2023-06-20T16:34:03.133004+00:00","id":3135,"links":{},"metadata":{"_buckets":{"deposit":"e693ca7c-6668-482d-bab4-9e09516722f6"},"_deposit":{"created_by":3,"id":"3135","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3135"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00003135","sets":["14:2667:2689:2693","21:2669:2691:2694"]},"author_link":["3471"],"item_8_alternative_title_3":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Electrochemical reactions in aqueous media by utilizing the activated carbon fiber porous reaction field modified with optically active thermoresponsive polymers"}]},"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-01-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"6","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費補助金研究成果報告書 (2010. )"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要(和文):温度上昇により水中で疎水的な環境を生み出す熱応答性高分子に、アミノ酸由来の光学活性部位を導入し、立体選択的な有機化合物の捕集ならびに水中での環境調和型有機反応を可能とする新規機能性高分子の合成に成功した。さらに、これらの高分子を炭素材料に固定化する手法を確立し、その表面状態を詳細に確認するとともに、水中での有機反応を実施し、機能性電極としての特性を評価したところ、表面に導入した熱応答性高分子の温度変化に伴う相転移現象に対応した電解反応のスイッチング現象を示唆する結果を得た。　　　　研究成果の概要(英文): Optically active thermoresponsive polymers have been newly synthesized by polymerization of amino acid-derived acrylamide type monomers. The resulting polymers have successfully applied for the stereoselective encapsulation of organic molecules and environmental benign organic reactions. Moreover the thermoresponsive polymers have been fixed on the carbon-based materials by using living radical polymerization technique. The resulting functionalized carbon-based composites have been characterized in detail and used as functional electrodes in several electrochemical model reactions in aqueous media. Preliminary results in dicating the switching phenomena of the electron transfer on the electrode were also obtained.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：基盤研究(C);  研究期間：2008～2010;   課題番号：20550104;   研究分野：有機化学;   科研費の分科・細目：複合化学・合成化学","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/r/40268462"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"ISHIFUNE, MANABU"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学理工学部; 准教授"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"石船,  学"},{"creatorName":"イシフネ, マナブ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"3471","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"40268462","nameIdentifierScheme":"研究者番号","nameIdentifierURI":" "}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-17"}],"displaytype":"detail","filename":"KAKEN_20550104seika.pdf","filesize":[{"value":"2.5 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KAKEN_20550104seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/3135/files/KAKEN_20550104seika.pdf"},"version_id":"4063a566-dfa7-408c-a45d-a690ec957c79"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"炭素材料","subitem_subject_scheme":"Other"},{"subitem_subject":"熱応答性高分子","subitem_subject_scheme":"Other"},{"subitem_subject":"光学活性高分子","subitem_subject_scheme":"Other"},{"subitem_subject":"水溶媒","subitem_subject_scheme":"Other"},{"subitem_subject":"グラフト重合","subitem_subject_scheme":"Other"},{"subitem_subject":"修飾電極","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"光学活性熱応答性高分子を固定化した活性炭素繊維細孔反応場における水中電解反応","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"光学活性熱応答性高分子を固定化した活性炭素繊維細孔反応場における水中電解反応"}]},"item_type_id":"8","owner":"3","path":["2693","2694"],"pubdate":{"attribute_name":"公開日","attribute_value":"2011-07-08"},"publish_date":"2011-07-08","publish_status":"0","recid":"3135","relation_version_is_last":true,"title":["光学活性熱応答性高分子を固定化した活性炭素繊維細孔反応場における水中電解反応"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-06-21T01:45:31.041842+00:00"}