{"created":"2023-06-20T16:34:03.048253+00:00","id":3133,"links":{},"metadata":{"_buckets":{"deposit":"ae8d2e3d-578f-4f13-8ea8-b533b65648a7"},"_deposit":{"created_by":3,"id":"3133","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3133"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00003133","sets":["14:2667:2689:2693","21:2669:2691:2694"]},"author_link":["3466"],"item_8_alternative_title_3":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Self-assembly of novel metallamacrocycles as a functional anion receptors"}]},"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-01-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"5","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費補助金研究成果報告書 (2010. )"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要（和文）：対アニオンの異なる種々のCu(I)親錯体と3種の4,4'–ビピリミジン類縁配位子を合目的に組み合わせることにより，13種の新規な配位高分子・メタラマクロサイクリックエチレン付加体が自己集積化できることを見出し，特にその生成過程における対アニオンならびに合成溶媒選択性の役割を系統的に解明にした。これら新規化合物はいずれも数少ないアニオンレセプターとなりうるのみならず，熱的に安定な多核Cu(I)–エチレン付加体を単離・単結晶化できたことは，化学吸着サイトの構築や触媒作用の発現などへの応用が期待される。        研究成果の概要（ 英文）： The C2H4 adducts of novel 13 Cu(I) coordination polymers and metallamacrocycles were self–assembled by the combinations of parent Cu(I) complexes with different counter anions and three 4,4'–bipyrimidine derivatives. The roles of counter anions and reaction solvents were systematically proved in the formation processes. These new compounds are expected to become as a potential anion receptor. In addition, thermally stable polynuclear Cu(I) ethylene adducts are useful to construct the chemical adsorption and the catalytic reaction sites.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：基盤研究(C);  研究期間：2008～2010;   課題番号：20550069 ;  研究分野：化学;   科研費の分科・細目：基礎化学・無機化学","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/ja/r/70229293"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"MAEKAWA, MASAHIKO"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学理工学総合研究所; 教授"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"前川,  雅彦"},{"creatorName":"マエカワ, マサヒコ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-17"}],"displaytype":"detail","filename":"KAKEN_20550069seika.pdf","filesize":[{"value":"983.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KAKEN_20550069seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/3133/files/KAKEN_20550069seika.pdf"},"version_id":"b7de63df-207c-4293-a58e-c9c0073c27a7"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Cu(I)錯体","subitem_subject_scheme":"Other"},{"subitem_subject":"エチレン付加体","subitem_subject_scheme":"Other"},{"subitem_subject":"配位高分子","subitem_subject_scheme":"Other"},{"subitem_subject":"メタラマクロサイクリック","subitem_subject_scheme":"Other"},{"subitem_subject":"アニオンレセプター","subitem_subject_scheme":"Other"},{"subitem_subject":"自己集積化","subitem_subject_scheme":"Other"},{"subitem_subject":"分子認識","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"アニオン捕捉能を有する新規なメタラマクロサイクリック化合物の自己集積化","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"アニオン捕捉能を有する新規なメタラマクロサイクリック化合物の自己集積化"}]},"item_type_id":"8","owner":"3","path":["2693","2694"],"pubdate":{"attribute_name":"公開日","attribute_value":"2011-07-08"},"publish_date":"2011-07-08","publish_status":"0","recid":"3133","relation_version_is_last":true,"title":["アニオン捕捉能を有する新規なメタラマクロサイクリック化合物の自己集積化"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-06-21T01:45:35.379218+00:00"}