{"created":"2023-06-20T16:33:59.820957+00:00","id":3066,"links":{},"metadata":{"_buckets":{"deposit":"1b2040ff-fb3f-4322-bc0b-f742d65ef613"},"_deposit":{"created_by":3,"id":"3066","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3066"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00003066","sets":["14:2667:2695:2699","21:2669:2697:2700"]},"author_link":["3339","3342","3340","3341","3343"],"item_8_alternative_title_3":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Deperopment of solvent-free reaction process using solid desperse"}]},"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-01-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"4","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費補助金研究成果報告書 (2009. )"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"粉体分散媒と光触媒粉体の混合物上、酸素雰囲気下でのブラックライト照射によるシクロオクテンの光エポキシ化反応を行った。フルオロアパタイト上で尿素過酸化水素化合物とリンモリブデン酸テトラブチルアンモニウム触媒を用いて、スルフィドからスルホキサイドおよびスルホンへの新しい無溶媒酸化反応方法を開発してきた。光学活性スルホキシドの合成のために我々の無溶媒反応システムに不斉源を導入したところ、不斉酸化反応が構築されることが示された。（英文） We applied the solvent-free reaction system for cyclooctene photoepxdation under oxygen atomosphere irradiating of black light over mixture of SiO2powderdisperse and photocatalyst powder. we have previously developed A new synthetic method of sulfoxides and sulfones using solvent-free oxidations of sulfides with urea-hydrogen peroxide complex (urea-H2O2)and tetrabutylammonium phosphomolybdate catalyst on fluorapatite((Bu4N)3[PMo12O40]/FAp). For chiral sulfoxides, our methodology included the use of chial auxiliaries that were shown to affect the asymmetric oxidations.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：基盤研究(C)研究期間：2007～2009課題番号：19550154研究分野：無機化学、触媒合成科研費の分科・細目：環境学・環境技術・環境材料","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://rns.nii.ac.jp/nr/1000070205871"}]},{"subitem_relation_name":[{"subitem_relation_name_text":"http://rns.nii.ac.jp/nr/1000020278740"}]},{"subitem_relation_name":[{"subitem_relation_name_text":"http://rns.nii.ac.jp/nr/1000030088471"}]},{"subitem_relation_name":[{"subitem_relation_name_text":"http://rns.nii.ac.jp/nr/1000060110772"}]},{"subitem_relation_name":[{"subitem_relation_name_text":"http://rns.nii.ac.jp/nr/1000040167698"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"},{"subitem_text_value":"研究分担者"},{"subitem_text_value":"研究分担者"},{"subitem_text_value":"連携研究者"},{"subitem_text_value":"連携研究者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"SASAKI, YO"},{"subitem_text_language":"en","subitem_text_value":"IWASAKI, MITSUNOBU"},{"subitem_text_language":"en","subitem_text_value":"MORIMOTO, JUNJI"},{"subitem_text_language":"en","subitem_text_value":"ICHIHARA, JUNKO"},{"subitem_text_language":"en","subitem_text_value":"YAMAGUCHI, SHUNRO"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学・理工学部・講師"},{"subitem_text_value":"近畿大学・理工学部・准教授"},{"subitem_text_value":"近畿大学・理工学部・教授"},{"subitem_text_value":"大阪大学・産業科学研究所・助教"},{"subitem_text_value":"大阪大学・産業科学研究所・助教"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"佐々木,  洋"},{"creatorName":"ササキ, ヨウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"岩崎,  光伸"},{"creatorName":"イワサキ, ミツノブ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"森本,  純司"},{"creatorName":"モリモト, ジュンジ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"市原,  潤子"},{"creatorName":"イチハラ, ジュンコ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"山口,  俊朗"},{"creatorName":"ヤマグチ, シュンロウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-17"}],"displaytype":"detail","filename":"KAKEN_19550154seika.pdf","filesize":[{"value":"282.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KAKEN_19550154seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/3066/files/KAKEN_19550154seika.pdf"},"version_id":"c2b0a5cd-9afd-49f1-98fd-648158e981fc"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"グリーンケミストリー","subitem_subject_scheme":"Other"},{"subitem_subject":"無溶媒反応","subitem_subject_scheme":"Other"},{"subitem_subject":"触媒","subitem_subject_scheme":"Other"},{"subitem_subject":"粉体分散媒","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"固体分散相を用いた無溶媒反応プロセスの展開","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"固体分散相を用いた無溶媒反応プロセスの展開"}]},"item_type_id":"8","owner":"3","path":["2699","2700"],"pubdate":{"attribute_name":"公開日","attribute_value":"2010-07-06"},"publish_date":"2010-07-06","publish_status":"0","recid":"3066","relation_version_is_last":true,"title":["固体分散相を用いた無溶媒反応プロセスの展開"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-06-21T01:47:45.797938+00:00"}