{"created":"2023-06-20T16:33:58.148468+00:00","id":3029,"links":{},"metadata":{"_buckets":{"deposit":"f02feb40-c4e9-43f3-b955-8393dde1a1bd"},"_deposit":{"created_by":3,"id":"3029","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3029"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00003029","sets":["14:2667:2701:2702"]},"author_link":["3283"],"item_8_alternative_title_3":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Synthesis of Single-handed Helical Polymers from Racemic Monomerswith Enzymes and Their Application"}]},"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008-01-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"4","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費補助金研究成果報告書 (2008. )"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"一分子内にビニル基とアルデヒド基を有する4-(ビニルベンジルオキシ)ベンズアルデヒドの二価のヨウ化サマリウム(SmI_2)を用いた還元的カップリングにより、ビニル基を一分子内に二つ有するジオール化合物を合成することに成功した。この化合物は、二つのビニル基を有しているので、この点を利用して、ジチオールとのラジカル付加重合による主鎖中にキラルなジオール部位を有する高分子の合成や架橋剤としての応用、OH 基の修飾による機能性モノマーへの展開等が期待される。","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：若手研究(B);研究期間：2007～2008;課題番号：19750090;研究分野：化学;科研費の分科・細目：複合化学・高分子化学","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://rns.nii.ac.jp/nr/1000000362286"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"MORINO, KAZUHIDE"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学・分子工学研究所・講師"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"森野,  一英"},{"creatorName":"モリノ, カズヒデ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-17"}],"displaytype":"detail","filename":"KAKEN_19750090seika.pdf","filesize":[{"value":"433.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KAKEN_19750090seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/3029/files/KAKEN_19750090seika.pdf"},"version_id":"916fd9c3-4784-4a68-9002-77066ed6e1cc"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"高分子合成","subitem_subject_scheme":"Other"},{"subitem_subject":"らせん","subitem_subject_scheme":"Other"},{"subitem_subject":"光学活性","subitem_subject_scheme":"Other"},{"subitem_subject":"キラル","subitem_subject_scheme":"Other"},{"subitem_subject":"酵素","subitem_subject_scheme":"Other"},{"subitem_subject":"ヨウ化サマリウム","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"酵素を用いたラセミ体原料からの完全一方向巻きらせん高分子の創製と応用","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"酵素を用いたラセミ体原料からの完全一方向巻きらせん高分子の創製と応用"}]},"item_type_id":"8","owner":"3","path":["21","2702"],"pubdate":{"attribute_name":"公開日","attribute_value":"2010-01-16"},"publish_date":"2010-01-16","publish_status":"0","recid":"3029","relation_version_is_last":true,"title":["酵素を用いたラセミ体原料からの完全一方向巻きらせん高分子の創製と応用"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-06-21T01:48:52.416736+00:00"}