{"created":"2023-06-20T16:49:49.588608+00:00","id":22130,"links":{},"metadata":{"_buckets":{"deposit":"ff189a23-98b8-4d29-9bbb-4029afcc115a"},"_deposit":{"created_by":3,"id":"22130","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"22130"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00022130","sets":["14:2667:4710"]},"author_link":["43374","43413","43414","43415"],"control_number":"22130","item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"17","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2020)"}]}]},"item_8_description_25":{"attribute_name":"リンクURL","attribute_value_mlt":[{"subitem_description":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18K05280/","subitem_description_type":"Other"}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要（和文）：本研究の主要な研究成果は以下のとおりである。（1）金ナノ粒子担持酸化ニッケルに赤色光を照射することにより、金ナノ粒子から酸化ニッケルへの正孔移動が生じることを明らかにした。（2）銅アセチルアセトナートが触媒表面で酸素分子を挟んだ2核錯体を形成し、これにより選択的な酸素2電子還元反応が進行することで、高活性な過酸化水素合成が行えることを見出した。（3）金と銀の合金ナノ粒子が、金と銀それぞれのナノ粒子よりも高い局所電場増強効果を持つことを明らかにした。（4）ヘテロエピタキシャル接合を有する異種半導体複合担体により、長距離電荷分離を達成した。研究成果の概要（英文）：The main research results are as follows. (1) the irradiation of the red-light to Au nanoparticle-loaded nickel oxide induces the hot-hole transfer from Au nanoparticle to nickel oxide. (2) Two Copper acetylacetonate complexes form a dinuclear complex with oxygen molecules sandwiched on the surface of the catalyst, which promotes a selective oxygen two-electron reduction reaction, so that highly active hydrogen peroxide synthesis can be performed. (3) Au-Ag alloy nanoparticle possesses a higher local electric field enhancing effect as compared with that of gold and silver nanoparticle. (4) The heteronanostructured semiconductor with a heteroepitaxial junction enables long-range charge separation.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：基盤研究(C);  研究期間：2018～2020;   課題番号：18K05280;   研究分野：光電気化学;   科研費の分科・細目：","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ(WEKO2)","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"},{"subitem_text_value":"研究協力者"},{"subitem_text_value":"研究協力者"},{"subitem_text_value":"研究協力者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Naya, Shin-ichi"},{"subitem_text_language":"en","subitem_text_value":"Tada, Hiroaki"},{"subitem_text_language":"en","subitem_text_value":"Teranishi, Miwako"},{"subitem_text_language":"en","subitem_text_value":"Fujishima, Musashi"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学有害物質処理室; 技術職員"},{"subitem_text_value":"近畿大学理工学部応用化学科; 教授"},{"subitem_text_value":"近畿大学管理部施設管理課有害物質処理室; 技術職員"},{"subitem_text_value":"近畿大学理工学部応用化学科; 准教授"}]},"item_8_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"Kindai University"},{"subitem_text_value":"Kindai University"},{"subitem_text_value":"Kindai University"},{"subitem_text_value":"Kindai University"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_be7fb7dd8ff6fe43","subitem_version_type":"NA"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"納谷, 真一"},{"creatorName":"ナヤ, シンイチ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"多田, 弘明"},{"creatorName":"タダ, ヒロアキ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"寺西, 美和子"},{"creatorName":"テラニシ, ミワコ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"藤島, 武蔵"},{"creatorName":"フジシマ, ムサシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-11-08"}],"displaytype":"detail","filename":"18K05280seika.pdf","filesize":[{"value":"172.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"18K05280seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/22130/files/18K05280seika.pdf"},"version_id":"95f95b44-759c-446c-974e-f21ad7d3ab74"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"プラズモニック光触媒","subitem_subject_scheme":"Other"},{"subitem_subject":"太陽光","subitem_subject_scheme":"Other"},{"subitem_subject":"可視光","subitem_subject_scheme":"Other"},{"subitem_subject":"過酸化水素","subitem_subject_scheme":"Other"},{"subitem_subject":"酸素還元","subitem_subject_scheme":"Other"},{"subitem_subject":"局所電場増強効果","subitem_subject_scheme":"Other"},{"subitem_subject":"電荷分離","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"正孔移動型プラズモニック光触媒によるソーラー過酸化水素合成","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"正孔移動型プラズモニック光触媒によるソーラー過酸化水素合成","subitem_title_language":"ja"},{"subitem_title":"Hole-tansfer type plasmonic photocatalyst for solar hydrogen peroxide generation","subitem_title_language":"en"}]},"item_type_id":"8","owner":"3","path":["4710"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2021-11-08"},"publish_date":"2021-11-08","publish_status":"0","recid":"22130","relation_version_is_last":true,"title":["正孔移動型プラズモニック光触媒によるソーラー過酸化水素合成"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-08-13T05:59:27.568130+00:00"}