| Item type |
☆紀要論文 / Departmental Bulletin Paper(1) |
| 公開日 |
2021-07-30 |
| タイトル |
|
|
タイトル |
Synthesis and crystal structure of nickel(0) dicarbonyl complex with 4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole. [Ni(adpt)(CO)2]2・(adpt)2(thf) |
|
言語 |
en |
| 著者 |
Maekawa, Masahiko
Munakata, Megumu
Kuroda-Sowa, Takayoshi
Suenaga, Yusaku
|
| 言語 |
|
|
言語 |
jpn |
| キーワード |
|
|
主題 |
Nickel complexes, Carbonyl complexes, Crystal structures, Metal-CO bond |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
departmental bulletin paper |
| 著者 所属 |
|
|
値 |
近畿大学 |
| 著者 所属 |
|
|
値 |
近畿大学 |
| 著者 所属 |
|
|
値 |
近畿大学 |
| 著者 所属 |
|
|
値 |
近畿大学 |
| 著者所属(翻訳) |
|
|
値 |
Research Institute for Science and Technology, Kinki University |
| 著者所属(翻訳) |
|
|
値 |
Department of Chemistry, Kinki University |
| 著者所属(翻訳) |
|
|
値 |
Department of Chemistry, Kinki University |
| 著者所属(翻訳) |
|
|
値 |
Department of Chemistry, Kinki University |
| 版 |
|
|
出版タイプ |
NA |
|
出版タイプResource |
http://purl.org/coar/version/c_be7fb7dd8ff6fe43 |
| 出版者 名前 |
|
|
出版者 |
近畿大学理工学総合研究所 |
| 書誌情報 |
理工学総合研究所研究報告
en : Annual reports by Research Institute for Science and Technology
号 10,
p. 49-54,
発行日 1998-02-28
|
| ISSN |
|
|
収録物識別子タイプ |
ISSN |
|
収録物識別子 |
09162054 |
| 抄録 |
|
|
内容記述タイプ |
Abstract |
|
内容記述 |
[Abstract] A nickel(0) dicarbonyl complex [Ni(adpt)(CO)2]2・(adpt)2(thf) (1) (adpt=4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole) has been prepared and has been characterized crystallographically. Complex 1 has a triclinic, space group P1, a=11.473(6), b=15.779(3), c=8.179(1)Å, α=101.29(1), β=94.70(3), γ=102.87(3)°, V=1403.3(9)Å3, Z=1, R=0.036 and Rw=0.037. There includes two crystallographically different dicarbonyl nickel(0) complexes [Ni(adpt)(CO)2] (1a and 1b), two free adpt ligands and one solvated thf in a unit cell. On both complexes each Ni atom is coordinated by N atom from one side of two pyridyl groups in the coordinating adpt ligand, one N atom of triazole group and two terminal coordinating CO to provide the four-coordinate mononuclear structure in the distorted tetrahedral geometry. It was found that the Ni-CO bond is strengthened (shorter) and the C≡O bond is correspondingly weakened (longer), depending on the σ donation from N donor atom in the trans position. |
| フォーマット |
|
|
内容記述タイプ |
Other |
|
内容記述 |
application/pdf |
AN10074306-19980228-0049.pdf (657.8 kB)
