{"created":"2023-06-20T16:49:13.400503+00:00","id":21384,"links":{},"metadata":{"_buckets":{"deposit":"d87b9b21-1d3b-4ce5-9e4d-0f98efaa2f60"},"_deposit":{"created_by":3,"id":"21384","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"21384"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00021384","sets":["14:923:1711:4644"]},"author_link":["36506","36505"],"item_2_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-02-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"54","bibliographicPageEnd":"27","bibliographicPageStart":"23","bibliographic_titles":[{"bibliographic_title":"近畿大学工学部研究報告"},{"bibliographic_title":"Research reports of the Faculty of Engineering, Kindai University","bibliographic_titleLang":"en"}]}]},"item_2_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"[Abstract]For adamantyl resist, Ether was used as the solvent in the conventional synthetic method. Ether is an excellent solvent for organic synthesis reactions, as it is reaction-inactive and has the property of dissolving many organic compounds at the same time, and because it has a low boiling point (34.5℃), it can be easily removed from the extract and recovered by distillation. Is. However, the industrial use of Ether is extremely volatile and flammable, which is extremely dangerous. In this study, we decided to synthesize adamantane resist using THF as a solvent and Grignard reagent as a reactant. The purpose was to synthesize adamantanol, which is an alcoholic substance required as a precursor of this. Here, the THF used in this experiment is a 5-membered ring Ether, which is widely used as a solvent for the reaction, but is generally used for a reduction reaction with LiAlH4, a Grignard reagent, and a reaction using an organic Li reagent. Grignard reagents act as nucleophiles for carbonyl compounds. The R group of the Grignard reagent attacks the carbonyl carbon to form a new carbon-carbon bond. The product is an alkoxide, which is hydrolyzed to an alcohol. Using this solvent, 2-Methyl-2-adamantanol required as a precursor was synthesized by 2-Adamantanone and Grgnard reagents Methyl magunesium Chloride and Methyl magunesium bromide.","subitem_description_type":"Abstract"}]},"item_2_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学工学部"}]},"item_2_source_id_22":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2434592X","subitem_source_identifier_type":"ISSN"}]},"item_2_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"NOMURA,Masato"},{"subitem_text_language":"en","subitem_text_value":"MURAI,Yoshihiro"}]},"item_2_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学; 名誉教授"},{"subitem_text_value":"近畿大学全学共通教育機構"}]},"item_2_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"Professor Emeritus of Kindai University"},{"subitem_text_value":"General Education Coordinating Comunitee, Kindai University"}]},"item_2_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_be7fb7dd8ff6fe43","subitem_version_type":"NA"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"野村, 正人"},{"creatorName":"ノムラ, マサト","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"36505","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"村井, 義洋"},{"creatorName":"ムライ, ヨシヒロ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"36506","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-03-05"}],"displaytype":"detail","filename":"AN00063799-20210220-0023.pdf","filesize":[{"value":"1.1 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"AN00063799-20210220-0023.pdf","url":"https://kindai.repo.nii.ac.jp/record/21384/files/AN00063799-20210220-0023.pdf"},"version_id":"8a5c5ae4-8fc4-413e-9130-cf48b46994da"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Adamantyl resist","subitem_subject_scheme":"Other"},{"subitem_subject":"Grignard reagent","subitem_subject_scheme":"Other"},{"subitem_subject":"2-Methyl-2-adamantanol","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"〈研究論文〉Grignard 反応によるレジスト材料の開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"〈研究論文〉Grignard 反応によるレジスト材料の開発"},{"subitem_title":"〈Original Papers〉Development of resist material by Grignard reaction","subitem_title_language":"en"}]},"item_type_id":"2","owner":"3","path":["4644"],"pubdate":{"attribute_name":"公開日","attribute_value":"2021-03-05"},"publish_date":"2021-03-05","publish_status":"0","recid":"21384","relation_version_is_last":true,"title":["〈研究論文〉Grignard 反応によるレジスト材料の開発"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T21:08:39.738348+00:00"}