{"created":"2023-06-20T16:48:42.468095+00:00","id":20723,"links":{},"metadata":{"_buckets":{"deposit":"2394cd62-e18e-4e1f-a1cb-a8bd0b4513f8"},"_deposit":{"created_by":3,"id":"20723","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"20723"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00020723","sets":["14:2667:4550"]},"author_link":["30571","30572"],"control_number":"20723","item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"6","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2018)"}]}]},"item_8_description_25":{"attribute_name":"リンクURL","attribute_value_mlt":[{"subitem_description":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16K05874/","subitem_description_type":"Other"}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要（和文）：本研究は、ポルフィリン反応場としてのイオン液体の可能性を探求した。①TPPの金属錯体化としての反応場としてイオン液体が効果的であることを見出した。また、最も最適なイオン液体構造が[C8mim][Br]であることを明らかにした。②イオン液体中におけるNCPのソルバトクロミズムの調査では、イオン液体のアニオンに強い水素結合受容性がある場合、NCP外部窒素がNHとなる２H体を誘導し、アニオンに強い水素結合受容性が無い場合は、カチオンの水素結合供与性が働き、３H体を誘導し易いことが明らかになった。③キラルイオン液体を活用したプロキラルなNCPの不斉誘導可能であることを見出した。研究成果の概要（英文）：This work explored the potential of ionic liquids as porphyrin reaction media. ①It has been found that ionic liquids are effective as reaction media for metallation of TPP. In addition, we showed that the most suitable structure of ionic liquids is [C8mim] [Br]. ② The solvatochromism of N-confused porphyrin in ionic liquids were investigated. It has been revealed that ionic liquids with strong hydrogen bond accepter (anion) induce NCP-2H, while the ionic liquids with hydrogen bond donner (cation) induce NCP-3H.　③The ionic liquids with mandelate as an anion were prepared. The chiral properties of these mandelate type ionic liquids were clarified. We studied the chiral inducibility of prochiral N-confused porphyrin utilizing the mandelate type ionic liquids through the specific interaction.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：基盤研究(C);  研究期間：2016～2018;   課題番号：16K05874;   研究分野：有機化学;   科研費の分科・細目：","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ(WEKO2)","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"},{"subitem_text_value":"研究分担者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"KITAOKA, Satoshi"},{"subitem_text_language":"en","subitem_text_value":"NOBUOKA, Kaoru"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学工学部; 講師"},{"subitem_text_value":"大分大学理工学部; 准教授"}]},"item_8_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"Kindai University"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_be7fb7dd8ff6fe43","subitem_version_type":"NA"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"北岡, 賢"},{"creatorName":"キタオカ, サトシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"信岡, かおる"},{"creatorName":"ノブオカ, カオル","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-12"}],"displaytype":"detail","filename":"16K05874seika.pdf","filesize":[{"value":"384.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"16K05874seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/20723/files/16K05874seika.pdf"},"version_id":"55b3adc2-9db8-47cd-9476-dffc9b3a3560"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"イオン液体","subitem_subject_scheme":"Other"},{"subitem_subject":"ポルフィリン","subitem_subject_scheme":"Other"},{"subitem_subject":"グリーンケミストリー","subitem_subject_scheme":"Other"},{"subitem_subject":"キラル","subitem_subject_scheme":"Other"},{"subitem_subject":"キラル誘導","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"イオン液体が切り開くポルフィリン反応場のフロンティア","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"イオン液体が切り開くポルフィリン反応場のフロンティア","subitem_title_language":"ja"},{"subitem_title":"The Frontier of porphyrin reaction media generated by ionic liquids","subitem_title_language":"en"}]},"item_type_id":"8","owner":"3","path":["4550"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-03-12"},"publish_date":"2020-03-12","publish_status":"0","recid":"20723","relation_version_is_last":true,"title":["イオン液体が切り開くポルフィリン反応場のフロンティア"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-09-21T06:03:20.040304+00:00"}