{"created":"2023-06-20T16:48:28.075348+00:00","id":20372,"links":{},"metadata":{"_buckets":{"deposit":"d557a9ed-bb7b-4231-a297-0352fefa2c02"},"_deposit":{"created_by":3,"id":"20372","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"20372"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00020372","sets":["14:923:2261:4541"]},"author_link":["34777","34778"],"item_2_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-10","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"87","bibliographicPageStart":"83","bibliographicVolumeNumber":"10","bibliographic_titles":[{"bibliographic_title":"近畿大学次世代基盤技術研究所報告"},{"bibliographic_title":"Annual Report of Fundamental Technology for Next Generation Research Institute, Kindai University","bibliographic_titleLang":"en"}]}]},"item_2_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Metalation of porphyrins is usually carried out in a carefully chosen solvent that offers mutual solubility to both the metal salt and free-base porphyrin. However, these methods suffer from certain disadvantages, such as slow reaction rates, low yields, high boiling solvents.  Recently, it has become clear that several ionic liquids dissolve both porphyrins and metal salts.  Herein, we reported that metalation of TPP utilizing ionic liquids.  In [C8mim][Br], Cu(Ⅱ)-TPP complex is obtained 79 % yields.  In the presentation, we report detail reaction condition and effective ionic liquids structure for the metalation.","subitem_description_type":"Abstract"}]},"item_2_description_34":{"attribute_name":"目次","attribute_value_mlt":[{"subitem_description":"Ⅲ.論文集","subitem_description_type":"Other"}]},"item_2_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学次世代基盤技術研究所"}]},"item_2_source_id_22":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"21858802","subitem_source_identifier_type":"ISSN"}]},"item_2_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"KITAOKA,Satoshi"},{"subitem_text_language":"en","subitem_text_value":"HORI,Tetsuro"}]},"item_2_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学エ学部化学生命工学科; 講師: 近畿大学次世代基盤技術研究所; 講師"},{"subitem_text_value":"近畿大学大学院システムエ学研究科システムエ学専攻; 博士前期課程"}]},"item_2_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"Kindai University"},{"subitem_text_value":"Kindai University"}]},"item_2_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_be7fb7dd8ff6fe43","subitem_version_type":"NA"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"北岡, 賢"},{"creatorName":"キタオカ, サトシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"堀, 哲郎"},{"creatorName":"ホリ, テツロウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-11-15"}],"displaytype":"detail","filename":"AA12517632-20191000-0083.pdf","filesize":[{"value":"701.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"AA12517632-20191000-0083.pdf","url":"https://kindai.repo.nii.ac.jp/record/20372/files/AA12517632-20191000-0083.pdf"},"version_id":"b5da456d-5557-41ec-abe9-13cc2aeac0db"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Ionic Liquids","subitem_subject_scheme":"Other"},{"subitem_subject":"Porphyrin","subitem_subject_scheme":"Other"},{"subitem_subject":"Green Chemistry","subitem_subject_scheme":"Other"},{"subitem_subject":"Metalation","subitem_subject_scheme":"Other"},{"subitem_subject":"Sustainable Chemistry","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"〈原著論文〉イオン液体を活用した効果的なテトラフェニルポルフィリンの銅(Ⅱ)錯体化","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"〈原著論文〉イオン液体を活用した効果的なテトラフェニルポルフィリンの銅(Ⅱ)錯体化"},{"subitem_title":"Effective Copper(Ⅱ) Metalation of Tetraphenylporphyrin Utilizing Ionic Liquids","subitem_title_language":"en"}]},"item_type_id":"2","owner":"3","path":["4541"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-11-15"},"publish_date":"2019-11-15","publish_status":"0","recid":"20372","relation_version_is_last":true,"title":["〈原著論文〉イオン液体を活用した効果的なテトラフェニルポルフィリンの銅(Ⅱ)錯体化"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T21:25:57.988372+00:00"}