{"created":"2024-10-24T05:31:07.311213+00:00","id":2001903,"links":{},"metadata":{"_buckets":{"deposit":"9e5ad9bf-b8d6-4859-8dba-2a2d688c6652"},"_deposit":{"created_by":42,"id":"2001903","owners":[42],"pid":{"revision_id":0,"type":"depid","value":"2001903"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:02001903","sets":["14:2667:1728522335637:1728523622287"]},"author_link":[],"item_1693381679919":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"=資源タイプ識別子":"http://purl.org/coar/resource_type/c_93fc","resourcetype":"report","resourceuri":"http://purl.org/coar/resource_type/c_93fc"}]},"item_30001_bibliographic_information17":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicNumberOfPages":"16","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2023)","bibliographic_titleLang":"ja"}]}]},"item_30001_creator2":{"attribute_name":"研究代表者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"34419","affiliationNameIdentifierScheme":"kakenhi"}],"affiliationNames":[{"affiliationName":"近畿大学","affiliationNameLang":"ja"},{"affiliationName":"Kindai University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"松尾, 司","creatorNameLang":"ja"},{"creatorName":"Matsuo, Tsukasa","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"90312800","nameIdentifierScheme":"e-Rad_Researcher"}]}]},"item_30001_description8":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"かさ高い縮環型立体保護基（Rind 基）の優れた立体保護効果を活用することで、ハロゲンが置換した高周期14族元素二価化学種である「ハロテトリレン」を創出し、種々の炭素二価化学種である「カルベン」との反応により、高周期14族元素－炭素二重結合化合物「ハロテトレン」や「ハロテトリレン－NHC付加体」「テトリリウムイリデンカチオン－NHCビス付加体」を合成した。それらの分子構造や化学結合について、実験化学と理論化学の両面から解明した。また、種々のアリール基とゲルマニウム－ゲルマニウム二重結合が共役した「π共役系ジゲルメン化合物」を合成し、分子構造と光電子物性について明らかにした。","subitem_description_language":"ja","subitem_description_type":"Abstract"},{"subitem_description":"Halogen-substituted divalent species of heavier group 14 elements, halotetrylenes, have been obtained by taking advantage of the excellent steric protection of the fused-ring bulky Rind groups. The reactions between the halotetrylenes and various carbenes such as triplet carbenes and singlet N-heterocyclic carbenes (NHC) have been investigated, producing heavier group 14 elements-carbon doubly-bonded species, halotetrenes, and halotetrylene-NHC adducts and tetryliumylidene ions-bis-NHC adducts. The molecular structures and chemical bonding of the resulting unsaturated compounds have been elucidated by the experimental and theoretical studies. A series of π-conjugated digermene compounds, in which various aryl groups are conjugated with Ge=Ge double bonds, have also been synthesized, and their structures and electronic properties have been investigated.","subitem_description_language":"en","subitem_description_type":"Abstract"},{"subitem_description":"研究分野：元素化学","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_30001_file22":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","filename":"21K05091seika.pdf","filesize":[{"value":"301.9 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"url":"https://kindai.repo.nii.ac.jp/record/2001903/files/21K05091seika.pdf"},"version_id":"9ac840ae-34a3-48b7-ad08-00ac36d2bbe3"}]},"item_30001_funding_reference15":{"attribute_name":"助成情報","attribute_value_mlt":[{"subitem_award_numbers":{"subitem_award_number":"21K05091","subitem_award_uri":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21K05091/"},"subitem_award_titles":[{"subitem_award_title":"高度に分極した高周期14族元素－炭素多重結合化学種の合成と反応性の探究","subitem_award_title_language":"ja"},{"subitem_award_title":"Synthesis and reactivity of heavier group 14 elements-carbon multiple-bond species with a highly polarized structure","subitem_award_title_language":"en"}],"subitem_funder_names":[{"subitem_funder_name":"独立行政法人日本学術振興会","subitem_funder_name_language":"ja"},{"subitem_funder_name":"Japan Society for the Promotion of Science","subitem_funder_name_language":"en"}]}]},"item_30001_language10":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_30001_subject7":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"典型元素","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"主要族元素","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"多重結合","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"不飽和結合","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"テトリレン","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"テトレン","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"カルベン","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"立体保護基","subitem_subject_language":"ja","subitem_subject_scheme":"Other"}]},"item_30001_title0":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"高度に分極した高周期14族元素－炭素多重結合化学種の合成と反応性の探究","subitem_title_language":"ja"},{"subitem_title":"Synthesis and reactivity of heavier group 14 elements-carbon multiple-bond species with a highly polarized structure","subitem_title_language":"en"}]},"item_30001_version_type12":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_title":"高度に分極した高周期14族元素－炭素多重結合化学種の合成と反応性の探究","item_type_id":"40001","owner":"42","path":["1728523622287"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2024-10-24"},"publish_date":"2024-10-24","publish_status":"0","recid":"2001903","relation_version_is_last":true,"title":["高度に分極した高周期14族元素－炭素多重結合化学種の合成と反応性の探究"],"weko_creator_id":"42","weko_shared_id":-1},"updated":"2024-11-25T02:35:24.695879+00:00"}