{"created":"2023-11-08T05:50:38.297892+00:00","id":2000353,"links":{},"metadata":{"_buckets":{"deposit":"a569780d-7b08-42f9-a9d7-e8739e51c051"},"_deposit":{"created_by":42,"id":"2000353","owners":[42],"pid":{"revision_id":0,"type":"depid","value":"2000353"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:02000353","sets":["14:2667:1697004343623"]},"author_link":[],"item_1693381679919":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"report","resourceuri":"http://purl.org/coar/resource_type/c_93fc"}]},"item_30001_bibliographic_information17":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicNumberOfPages":"8","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2022)","bibliographic_titleLang":"ja"}]}]},"item_30001_creator2":{"attribute_name":"研究代表者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"34419","affiliationNameIdentifierScheme":"kakenhi"}],"affiliationNames":[{"affiliationName":"近畿大学","affiliationNameLang":"ja"},{"affiliationName":"Kindai University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"湯浅, 雅賀","creatorNameLang":"ja"},{"creatorName":"Yuasa, Masayoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"50404075","nameIdentifierScheme":"e-Rad"}]}]},"item_30001_description8":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"本研究では、メカノケミカル反応で得られるグラフェン（MSG）について、「①酸素の電気化学反応（酸素還元、酸素発生）に対する活性の向上」と、「②酸素の電気化学反応以外の電気化学反応（グルコース酸化、二酸化炭素還元）への適用」に取り組んだ。その結果、①については、MSGは窒素や硫黄のドープで酸素発生活性が向上すること、そして、酸素還元活性には活性点数が影響するが酸素発生活性には活性点数ではなく活性点の質が大きく影響することがわかった。②については、MSGはグルコース酸化活性を有すること、そして、MSGは二酸化炭素還元活性を持たないが他の材料の二酸化炭素還元活性を補助する機能があることがわかった。","subitem_description_language":"ja","subitem_description_type":"Abstract"},{"subitem_description":"Mechanochemically-synthesized graphene (MSG) was investigated as an electrode material for the oxygen reduction/evolution reaction, glucose oxidation and CO2 reduction. As a result, nitrogen and sulfur-doping enhanced the oxygen evolution activity of MSG. Moreover, we found that the surface area is important for the fabrication of MSG with high oxygen reduction activity and that the intrinsic oxygen evolution activity rather than the surface area is important for in the fabrication of MSG with high oxygen evolution activity. MSG showed high glucose oxidation activity. Although MSG itself did not exhibit CO2 reduction activity, it assisted the CO2 reduction activity of other catalysts.","subitem_description_language":"en","subitem_description_type":"Abstract"},{"subitem_description":"研究分野：無機材料化学","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_30001_file22":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","filename":"20K05693seika.pdf","format":"application/pdf","mimetype":"application/pdf","url":{"url":"https://kindai.repo.nii.ac.jp/record/2000353/files/20K05693seika.pdf"},"version_id":"ec13f946-1185-452b-b071-70bf1b5e62f5"}]},"item_30001_funding_reference15":{"attribute_name":"助成情報","attribute_value_mlt":[{"subitem_award_numbers":{"subitem_award_number":"20K05693","subitem_award_uri":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20K05693/"},"subitem_award_titles":[{"subitem_award_title":"機能化ナノカーボンのメカノケミカル合成と電気化学エネルギー変換デバイスへの応用","subitem_award_title_language":"ja"},{"subitem_award_title":"Mechanochemical Synthesis of Functionalized Nano-carbons for Electrochemical Energy Conversion Devices","subitem_award_title_language":"en"}],"subitem_funder_names":[{"subitem_funder_name":"独立行政法人日本学術振興会","subitem_funder_name_language":"ja"},{"subitem_funder_name":"Japan Society for the Promotion of Science","subitem_funder_name_language":"en"}]}]},"item_30001_language10":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_30001_subject7":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"グラフェン 　\n","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"メカノケミカル反応　","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"酸素還元反応 　","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"酸素発生反応 　","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"金属空気電池 　","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"グルコース燃料電池　","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"二酸化炭素還元","subitem_subject_language":"ja","subitem_subject_scheme":"Other"}]},"item_30001_title0":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"機能化ナノカーボンのメカノケミカル合成と電気化学エネルギー変換デバイスへの応用\n","subitem_title_language":"ja"},{"subitem_title":"Mechanochemical Synthesis of Functionalized Nano-carbons for Electrochemical Energy Conversion Devices","subitem_title_language":"en"}]},"item_30001_version_type12":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_title":"機能化ナノカーボンのメカノケミカル合成と電気化学エネルギー変換デバイスへの応用\n","item_type_id":"40001","owner":"42","path":["1697004343623"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-11-08"},"publish_date":"2023-11-08","publish_status":"0","recid":"2000353","relation_version_is_last":true,"title":["機能化ナノカーボンのメカノケミカル合成と電気化学エネルギー変換デバイスへの応用\n"],"weko_creator_id":"42","weko_shared_id":-1},"updated":"2024-02-09T05:14:24.475752+00:00"}