{"created":"2023-11-08T01:38:19.879854+00:00","id":2000321,"links":{},"metadata":{"_buckets":{"deposit":"ab0ed00d-9534-406b-9177-05e90bc5991b"},"_deposit":{"created_by":42,"id":"2000321","owners":[42],"pid":{"revision_id":0,"type":"depid","value":"2000321"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:02000321","sets":["14:2667:1697004343623"]},"author_link":[],"item_1693378644159":{"attribute_name":"研究分担者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"11501","affiliationNameIdentifierScheme":"kakenhi"}],"affiliationNames":[{"affiliationName":"山形大学","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"安東, 秀峰","creatorNameLang":"ja"},{"creatorName":"Ando, Hideo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"00754946","nameIdentifierScheme":"e-Rad"}]}]},"item_1693381679919":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"report","resourceuri":"http://purl.org/coar/resource_type/c_93fc"}]},"item_30001_bibliographic_information17":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicNumberOfPages":"12","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2022)","bibliographic_titleLang":"ja"}]}]},"item_30001_creator2":{"attribute_name":"研究代表者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"34419","affiliationNameIdentifierScheme":"kakenhi"}],"affiliationNames":[{"affiliationName":"近畿大学","affiliationNameLang":"ja"},{"affiliationName":"Kindai University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"松本, 浩一","creatorNameLang":"ja"},{"creatorName":"Matsumoto, Kouichi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"60581741","nameIdentifierScheme":"e-Rad"}]}]},"item_30001_description8":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"中央上部に三方コックを導入した分離型電解セルを用いた両極合成と溶液混合により、エノールシリルエーテルとチオフェノールから、アセトフェノンのα位への硫黄導入が低い収率ながら進行することを見出した。また陽極発生イミニウムイオンと陰極でのin-stu調製したアリルシランとの溶液移動を伴う結合形成反応や、含硫黄アリル化合物の合成などにも成功した。その他、電解合成や非電解合成、あるいは計算化学による解明など、多くの成果を得ることに成功した。","subitem_description_language":"ja","subitem_description_type":"Abstract"},{"subitem_description":"We have designed and developed the new type of divided cell, in which three-way cock was incorporated in the center position of the cell, which enables the electrolyzed cathodic solution to transfer into anodic chamber by using the balloon after the electrolysis. As the examples of the successful results, the electrolysis of enol silyl ether in the anode and PhSH in the cathode and the solution transfer gave the corresponding the PhS-contained product, despite of the low yields. The paired electrolysis of in-situ generated iminium cation and allylsilanes and the solution transfer gave the products of C-C bond formations. Besides, various successful results containing the electro- and non-electro- synthesis were obtained for 3 years.","subitem_description_language":"en","subitem_description_type":"Abstract"},{"subitem_description":"研究分野：有機合成化学、有機電解合成、有機反応開発","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_30001_file22":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","filename":"20K05588seika.pdf","format":"application/pdf","mimetype":"application/pdf","url":{"url":"https://kindai.repo.nii.ac.jp/record/2000321/files/20K05588seika.pdf"},"version_id":"660ec896-4bb6-41d9-94c2-7589cf7ce3aa"}]},"item_30001_funding_reference15":{"attribute_name":"助成情報","attribute_value_mlt":[{"subitem_award_numbers":{"subitem_award_number":"20K05588","subitem_award_uri":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20K05588/"},"subitem_award_titles":[{"subitem_award_title":"溶液移動が可能な新規分離型電解セルを用いた含イオウ化合物の低環境負荷型両極合成","subitem_award_title_language":"ja"},{"subitem_award_title":"Environment-friendly paired electro-synthesis of sulfur compounds using divided cell equipped with solution transfer","subitem_award_title_language":"en"}],"subitem_funder_names":[{"subitem_funder_name":"独立行政法人日本学術振興会","subitem_funder_name_language":"ja"},{"subitem_funder_name":"Japan Society for the Promotion of Science","subitem_funder_name_language":"en"}]}]},"item_30001_language10":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_30001_subject7":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"両極電解合成","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"有機活性種","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"分離型電解セル","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"溶液移動セル","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"結合形成反応","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"イオウ化合物","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"計算化学","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"アリルシラン","subitem_subject_language":"ja","subitem_subject_scheme":"Other"}]},"item_30001_title0":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"溶液移動が可能な新規分離型電解セルを用いた含イオウ化合物の低環境負荷型両極合成","subitem_title_language":"ja"},{"subitem_title":"Environment-friendly paired electro-synthesis of sulfur compounds using divided cell equipped with solution transfer","subitem_title_language":"en"}]},"item_30001_version_type12":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_title":"溶液移動が可能な新規分離型電解セルを用いた含イオウ化合物の低環境負荷型両極合成","item_type_id":"40001","owner":"42","path":["1697004343623"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-11-08"},"publish_date":"2023-11-08","publish_status":"0","recid":"2000321","relation_version_is_last":true,"title":["溶液移動が可能な新規分離型電解セルを用いた含イオウ化合物の低環境負荷型両極合成"],"weko_creator_id":"42","weko_shared_id":-1},"updated":"2024-02-09T05:50:04.644475+00:00"}