{"created":"2023-11-08T01:37:34.754139+00:00","id":2000310,"links":{},"metadata":{"_buckets":{"deposit":"6ad7a32a-387d-406a-8b41-c5cbb0c0b93d"},"_deposit":{"created_by":42,"id":"2000310","owners":[42],"pid":{"revision_id":0,"type":"depid","value":"2000310"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:02000310","sets":["14:2667:1697004343623"]},"author_link":[],"item_1693381679919":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"report","resourceuri":"http://purl.org/coar/resource_type/c_93fc"}]},"item_30001_bibliographic_information17":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicNumberOfPages":"8","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2022)","bibliographic_titleLang":"ja"}]}]},"item_30001_creator2":{"attribute_name":"研究代表者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"34419","affiliationNameIdentifierScheme":"kakenhi"}],"affiliationNames":[{"affiliationName":"近畿大学","affiliationNameLang":"ja"},{"affiliationName":"Kindai University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"中村, 光","creatorNameLang":"ja"},{"creatorName":"Nakamura, Akira","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"50706629","nameIdentifierScheme":"e-Rad"}]}]},"item_30001_description8":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"過去の研究から得た知見をもとにN―ヒドロキシアミノ基の特性に着目した反応の開拓を行った。N―ヒドロキシアミド構造であるヒドロキサム酸の変換に関して、ハロゲン化合物を触媒とした加溶媒分解の開発を行った。カルボン酸への変換は室温下でヒドロキサム酸を官能基選択的にカルボン酸に変換できることを明らかにした。またオキシムを利用した複素環の合成法として、二置換テトラゾール類を室温下で合成する新たな反応条件を見出した。また入手容易なカルコン類を用いて、生物活性化合物中に含まれる複素環化合物の新規合成法の開発を行った。","subitem_description_language":"ja","subitem_description_type":"Abstract"},{"subitem_description":"For the conversion of hydroxamic acid, an N-hydroxyamide structure, catalytic solvolysis using a halogen compound as a catalyst was developed. The conversion of hydroxamic acid to carboxylic acid was demonstrated under room temperature. In addition, as a method for the synthesis of heterocyclic compounds using oximes, new reaction conditions were found for the synthesis of disubstituted tetrazoles at room temperature. We also developed a new synthetic method for the synthesis of heterocyclic compounds in biologically active compounds using readily available chalcones.","subitem_description_language":"en","subitem_description_type":"Abstract"},{"subitem_description":"研究分野：有機合成","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_30001_file22":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","filename":"19K16329seika.pdf","format":"application/pdf","mimetype":"application/pdf","url":{"url":"https://kindai.repo.nii.ac.jp/record/2000310/files/19K16329seika.pdf"},"version_id":"db7b0599-9fb9-4c08-af70-36302056b9b4"}]},"item_30001_funding_reference15":{"attribute_name":"助成情報","attribute_value_mlt":[{"subitem_award_numbers":{"subitem_award_number":"19K16329","subitem_award_uri":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19K16329/"},"subitem_award_titles":[{"subitem_award_title":"N―ヒドロキシアミンの特性に基づく官能基選択的反応の開発","subitem_award_title_language":"ja"},{"subitem_award_title":"Development of functional group selective reactions based on the properties of N-hydroxyamines.","subitem_award_title_language":"en"}],"subitem_funder_names":[{"subitem_funder_name":"独立行政法人日本学術振興会","subitem_funder_name_language":"ja"},{"subitem_funder_name":"Japan Society for the Promotion of Science","subitem_funder_name_language":"en"}]}]},"item_30001_language10":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_30001_subject7":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"ヒドロキサム酸","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"カルコン","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"複素環合成","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"触媒反応","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"ハロゲン化合物","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"転位反応","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"加溶媒分解","subitem_subject_language":"ja","subitem_subject_scheme":"Other"}]},"item_30001_title0":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"N―ヒドロキシアミンの特性に基づく官能基選択的反応の開発","subitem_title_language":"ja"},{"subitem_title":"Development of functional group selective reactions based on the properties of N-hydroxyamines.","subitem_title_language":"en"}]},"item_30001_version_type12":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_title":"N―ヒドロキシアミンの特性に基づく官能基選択的反応の開発","item_type_id":"40001","owner":"42","path":["1697004343623"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-11-08"},"publish_date":"2023-11-08","publish_status":"0","recid":"2000310","relation_version_is_last":true,"title":["N―ヒドロキシアミンの特性に基づく官能基選択的反応の開発"],"weko_creator_id":"42","weko_shared_id":-1},"updated":"2024-02-09T05:49:31.998339+00:00"}