{"created":"2023-11-08T01:37:22.372699+00:00","id":2000307,"links":{},"metadata":{"_buckets":{"deposit":"94023662-d934-4619-b35d-60f94570d941"},"_deposit":{"created_by":42,"id":"2000307","owners":[42],"pid":{"revision_id":0,"type":"depid","value":"2000307"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:02000307","sets":["14:2667:1697004343623"]},"author_link":[],"item_1693381679919":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"report","resourceuri":"http://purl.org/coar/resource_type/c_93fc"}]},"item_30001_bibliographic_information17":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicNumberOfPages":"21","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2022)","bibliographic_titleLang":"ja"}]}]},"item_30001_creator2":{"attribute_name":"研究代表者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"34419","affiliationNameIdentifierScheme":"kakenhi"}],"affiliationNames":[{"affiliationName":"近畿大学","affiliationNameLang":"ja"},{"affiliationName":"Kindai University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"前川, 智弘","creatorNameLang":"ja"},{"creatorName":"Maegawa, Tomohiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"40363890","nameIdentifierScheme":"e-Rad"}]}]},"item_30001_description8":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"本研究では、硫黄化合物であるフェニルチオトリメチルシランをN-ブロモスクシンイミドととも用いることで、従来反応性が低かったＮ－ブロモスクシンイミドの反応性を大きく向上させることを見出し、以下の成果を得た。\n（１）電子密度が低く、N-ブロモスクシンイミドのみでは反応が進行しない芳香環の臭素化及び塩素化がフェニルチオトリメチルシランを添加することで効率的に進行することを見出した。\n（２）本試薬の組み合わせを用いることで環状アセタールから直接的なエステル化が進行することを見出した。\n（３）本試薬の組み合わせを用いることで、従来では進行しなかったラジカル反応が進行することを見出した。","subitem_description_language":"ja","subitem_description_type":"Abstract"},{"subitem_description":"In this study, we found that the reactivity of N-bromosuccinimide, whose reactivity was conventionally low, is greatly improved by using phenylthiotrimethylsilane, a sulfur compound, with N-bromosuccinimide.\n(1) Bromination and chlorination of relatively electron poor aromatic rings, which cannot proceed with N-bromosuccinimide alone, are efficiently promoted by the addition of phenylthiotrimethylsilane. \n(2) We found that direct esterification from cyclic acetals proceeded by using these reagents combination.\n(3) By using this reagent combination, we found that radical reactions proceed at room temperature.","subitem_description_language":"en","subitem_description_type":"Abstract"},{"subitem_description":"研究分野：有機反応化学","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_30001_file22":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","filename":"18K05132seika.pdf","format":"application/pdf","mimetype":"application/pdf","url":{"url":"https://kindai.repo.nii.ac.jp/record/2000307/files/18K05132seika.pdf"},"version_id":"912ee9da-ae11-4601-8d1d-8aece50defa0"}]},"item_30001_funding_reference15":{"attribute_name":"助成情報","attribute_value_mlt":[{"subitem_award_numbers":{"subitem_award_number":"18K05132","subitem_award_uri":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18K05132/"},"subitem_award_titles":[{"subitem_award_title":"硫黄化合物を用いる高活性なハロゲン化反応の開発とその応用","subitem_award_title_language":"ja"},{"subitem_award_title":"Development og highly reactive halogenation reaction using sulfur compound and its applications","subitem_award_title_language":"en"}],"subitem_funder_names":[{"subitem_funder_name":"独立行政法人日本学術振興会","subitem_funder_name_language":"ja"},{"subitem_funder_name":"Japan Society for the Promotion of Science","subitem_funder_name_language":"en"}]}]},"item_30001_language10":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_30001_subject7":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"ハロゲン化","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"硫黄化合物","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"活性化","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"N-ハロスクシンイミド","subitem_subject_language":"ja","subitem_subject_scheme":"Other"}]},"item_30001_title0":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"硫黄化合物を用いる高活性なハロゲン化反応の開発とその応用","subitem_title_language":"ja"},{"subitem_title":"Development og highly reactive halogenation reaction using sulfur compound and its applications","subitem_title_language":"en"}]},"item_30001_version_type12":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_title":"硫黄化合物を用いる高活性なハロゲン化反応の開発とその応用","item_type_id":"40001","owner":"42","path":["1697004343623"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-11-08"},"publish_date":"2023-11-08","publish_status":"0","recid":"2000307","relation_version_is_last":true,"title":["硫黄化合物を用いる高活性なハロゲン化反応の開発とその応用"],"weko_creator_id":"42","weko_shared_id":-1},"updated":"2024-02-09T05:49:26.344721+00:00"}