{"created":"2023-06-20T16:48:07.624717+00:00","id":19947,"links":{},"metadata":{"_buckets":{"deposit":"0d7c8b7f-fff0-4635-bda1-ea0255707c13"},"_deposit":{"created_by":3,"id":"19947","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"19947"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00019947","sets":["14:923:2091:4483"]},"author_link":["33981","33982","33983","33979","33980","33978","33984"],"item_2_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-02-28","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"30","bibliographicPageEnd":"10","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"理工学総合研究所研究報告"},{"bibliographic_title":"Annual reports by Science and Technology Research Institute","bibliographic_titleLang":"en"}]}]},"item_2_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"[Abstract] Three tri-nuclear cobalt complexes ([Co3(tpa)3(L)](BF4)4 (1) (tpa=tris(2-pyridylmethyl)amine),[Co3(Metpa)3(L)](BF4)4 (2) (Metpa=(6-methyl-2-pyridylmethyl)bis(2-pyridylmethyl)amine) and [Co3(Me2tpa)3(L)](BF4)3 (3) (Me2tpa=bis(6-methyl-2-pyridylmethyl)(2-pyridylmethyl)amine)) with 2,3,6,7,10,11hexahydroxytriphenylene (H6L) and three spieces ancillary ligands have been prepared. Tri-nuclear mixed-valence Co complex (3) is prepared from methanol solution. Complex (3) has consist in that the valence of two cobalt ions have +III,one cobalt ion has +II and the tris-dioxolene bridging ligand is formally in the -5 [cat,cat,sq] oxidation state. Complex (3) shows evidence of temperature dependence of the charge distribution, displaying thermally induced valence tautomeric transition from {(ls-CoIII)2(hs-CoII)}-L(cat,cat,sq) to {(ls-CoIII)(hs-CoII)2}-L(cat,sq,sq) in both solid and solution states. On the other hand, complex (1) and complex (2) are stable in the entire temperature range investigated.Various-temperature magnetic susceptibility data for the compound displayed little variation in the range 2-380 K, and the reason caused the distinct charge distribution on Co-L (L: bridging ligand) by the natural rigidity of the tripodal ligands. These results appeared methylation of the 6-position of the pyridine rings in ancillary ligand effect on redox state in the complex, occuring the distribution of electrons between the cobalt centers and the bridging ligand.","subitem_description_type":"Abstract"}]},"item_2_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学理工学総合研究所"}]},"item_2_source_id_22":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09162054","subitem_source_identifier_type":"ISSN"}]},"item_2_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学"},{"subitem_text_value":"近畿大学"},{"subitem_text_value":"近畿大学"},{"subitem_text_value":"近畿大学"},{"subitem_text_value":"近畿大学"},{"subitem_text_value":"近畿大学"},{"subitem_text_value":"近畿大学"}]},"item_2_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"Department of Science, Kindai University: Science and Technology Research Institute, Kindai University"},{"subitem_text_value":"Department of Science, Kindai University"},{"subitem_text_value":"Department of Science, Kindai University"},{"subitem_text_value":"Department of Science, Kindai University"},{"subitem_text_value":"Department of Science, Kindai University: Science and Technology Research Institute, Kindai University"},{"subitem_text_value":" Science and Technology Research Institute, Kindai University"},{"subitem_text_value":"Department of Science, Kindai University: Science and Technology Research Institute, Kindai University"}]},"item_2_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_be7fb7dd8ff6fe43","subitem_version_type":"NA"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Suenaga, Yusaku"},{"creatorName":"スエナガ, ユウサク","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"lnomata, Masataka"},{"creatorName":"イノマタ, マサタカ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yabumoto, Shiomi"},{"creatorName":"ヤブモト, シオミ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yamaguchi, Ryotaro"},{"creatorName":"ヤマグチ, リョウタロウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Okubo, Takashi"},{"creatorName":"オオクボ, タカシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Maekawa, Masahiko"},{"creatorName":"マエカワ, マサヒコ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Takayoshi, Kuroda-Sowa"},{"creatorName":"クロダ-ソワ, タカヨシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","displaytype":"detail","filename":"AN10074306-20180228-0001.pdf","filesize":[{"value":"2.6 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"url":"https://kindai.repo.nii.ac.jp/record/19947/files/AN10074306-20180228-0001.pdf"},"version_id":"ef4ef47c-1f11-4e05-9ce8-b294d8a0ddea"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Tri-nuclear Co complex","subitem_subject_scheme":"Other"},{"subitem_subject":"Hexahydroxy triphenylene","subitem_subject_scheme":"Other"},{"subitem_subject":"Valence tautomeric behavior","subitem_subject_scheme":"Other"},{"subitem_subject":"Electrochemical behavior, Magnetic property","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Valence Tautomeric Behavior of Tri-nuclear Mixed-Valence CoIII/CoII Complex containing 2, 3, 6, 7,10, 11-Hexahydroxytriphenylene (Ｈ6Ｌ)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Valence Tautomeric Behavior of Tri-nuclear Mixed-Valence CoIII/CoII Complex containing 2, 3, 6, 7,10, 11-Hexahydroxytriphenylene (Ｈ6Ｌ)","subitem_title_language":"en"}]},"item_type_id":"2","owner":"3","path":["4483"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-02-06"},"publish_date":"2019-02-06","publish_status":"0","recid":"19947","relation_version_is_last":true,"title":["Valence Tautomeric Behavior of Tri-nuclear Mixed-Valence CoIII/CoII Complex containing 2, 3, 6, 7,10, 11-Hexahydroxytriphenylene (Ｈ6Ｌ)"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T20:41:33.937671+00:00"}