{"created":"2023-06-20T16:47:55.268887+00:00","id":19698,"links":{},"metadata":{"_buckets":{"deposit":"339fe843-50e6-425e-a2af-b40947d017f6"},"_deposit":{"created_by":3,"id":"19698","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"19698"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00019698","sets":["14:2667:4459"]},"author_link":["33439"],"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"6","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2017)"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要（和文）：一般的手法により、左回転の光を出す円偏光発光（CPL)発光体、右回転の光を出すCPL発光体を得るには、有機合成的手法を用い、分子構造のどこかに、それぞれ右手と左手の関係にある不斉炭素（［R］および［S］）などの導入が必要である。本研究では，有機合成的手法をできるだけ回避し、光学活性な発光性分子を、各種物性を有する有機あるいは無機マトリックス中にドーピングすることにより、光の回転方向の制御に成功した。\n研究成果の概要（英文）：Chiral organic fluorophores (COFs) emitting circularly polarized luminescence (CPL) with a high quantum efficiency have recently garnered considerable attention in the field of chiral photoluminescence. Generally, to yield a pair of (+) and (-) CPL signals, it is necessary to design a pair of enantiopure COFs with opposite stereogenic centers. However, this approach has several practical limitations, as the preparation of such enantiomers may not always be possible. Herein, we demonstrated that the signs of the CPL and circular dichroism (CD) signals could be reversed by changing the external environment such as solvent.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：基盤研究(C);  研究期間：2015～2017;   課題番号：15K05489;   研究分野：円偏光発光;   科研費の分科・細目：","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15K05489/"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"IMAI,Yoshitane"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学理工学部; 准教授"}]},"item_8_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"Kindai University"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_be7fb7dd8ff6fe43","subitem_version_type":"NA"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"今井, 喜胤"},{"creatorName":"イマイ, ヨシタネ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"33439","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"80388496","nameIdentifierScheme":"研究者番号","nameIdentifierURI":" "}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-11-20"}],"displaytype":"detail","filename":"15K05489seika.pdf","filesize":[{"value":"2.8 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"15K05489seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/19698/files/15K05489seika.pdf"},"version_id":"80411058-473c-4dc5-a0d4-ec2e5a8c9a75"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"円偏光発光","subitem_subject_scheme":"Other"},{"subitem_subject":"CPL","subitem_subject_scheme":"Other"},{"subitem_subject":"キラル","subitem_subject_scheme":"Other"},{"subitem_subject":"光学活性","subitem_subject_scheme":"Other"},{"subitem_subject":"発光","subitem_subject_scheme":"Other"},{"subitem_subject":"蛍光","subitem_subject_scheme":"Other"},{"subitem_subject":"円偏光二色性","subitem_subject_scheme":"Other"},{"subitem_subject":"CD","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"マトリックスを利用した非古典的円編光発光スイッチ・増幅システムの構築","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"マトリックスを利用した非古典的円編光発光スイッチ・増幅システムの構築"},{"subitem_title":"Construction of non-classical circularly polarized luminescence (CPL) switch and amplification system using matrix","subitem_title_language":"en"}]},"item_type_id":"8","owner":"3","path":["4459"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-11-20"},"publish_date":"2018-11-20","publish_status":"0","recid":"19698","relation_version_is_last":true,"title":["マトリックスを利用した非古典的円編光発光スイッチ・増幅システムの構築"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T21:35:53.217971+00:00"}