{"created":"2023-06-20T16:47:10.805342+00:00","id":18812,"links":{},"metadata":{"_buckets":{"deposit":"ee241a71-5465-4708-b3ad-8ee54a374cc5"},"_deposit":{"created_by":3,"id":"18812","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"18812"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00018812","sets":["14:2667:4374"]},"author_link":["31792"],"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"5","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2016)"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要（和文）：生体反応系における感応性化学種の「機能モデル金属錯体」の開発を中心に研究を進めた。その結果、（i）光ネルギー変換において重要な役割を果たしている「光感応性化学種」および（ii）還元酵素における重要な中間体（感応性化学種）として知られている「低原子価金属種」の新規なモデル錯体を種々合成することに成功した。例えば、 （i）拡張性が高く、酸素応答性を有する強発光性のテルビウム錯体や（ii）酸素分子の水への還元反応を触媒できる新規なニッケル-鉄錯体などである。\n研究成果の概要（英文）：The research was mainly focused on the development of the “functional models (metal complexes)” of the stimuli-responsive bio-related chemical species. In this project, we have successfully synthesized new functional models of (i) “light-responsive chemical species” that play an important role in light energy conversion system and (ii) “low-valent metal species” that are known as reactive intermediates in reducing enzyme: for instance (i) a highly luminescent and highly oxygen-sensitive terbium complex with an extendable phenol pendant arm and (ii) an nickel-iron dinuclear complex that can catalyze reduction of dioxygen to water.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：新学術領域研究（研究領域提案型）;  研究期間：2015～2016;   課題番号：15H00953;   研究分野：錯体化学;   科研費の分科・細目：","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PLANNED-15H00953/"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"NAKAI, Hidetaka"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学理工学部; 准教授"}]},"item_8_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"Kindai University"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_be7fb7dd8ff6fe43","subitem_version_type":"NA"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"中井, 英隆"},{"creatorName":"ナカイ, ヒデタカ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"31792","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"70377399","nameIdentifierScheme":"研究者番号","nameIdentifierURI":" "}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-11-01"}],"displaytype":"detail","filename":"15H00953seika.pdf","filesize":[{"value":"1.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"15H00953seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/18812/files/15H00953seika.pdf"},"version_id":"f4753851-1c80-4087-9397-8ff44026cfb6"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"人工酵素","subitem_subject_scheme":"Other"},{"subitem_subject":"光感応性金属錯体","subitem_subject_scheme":"Other"},{"subitem_subject":"低原子価金属錯体","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"生体内感応性化学種を模倣した金属錯体の開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"生体内感応性化学種を模倣した金属錯体の開発"},{"subitem_title":"Development of metal complexes that mimic stimuli-responsive bio-related chemical species","subitem_title_language":"en"}]},"item_type_id":"8","owner":"3","path":["4374"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-11-01"},"publish_date":"2017-11-01","publish_status":"0","recid":"18812","relation_version_is_last":true,"title":["生体内感応性化学種を模倣した金属錯体の開発"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T21:49:09.927973+00:00"}