{"created":"2023-06-20T16:47:10.496319+00:00","id":18807,"links":{},"metadata":{"_buckets":{"deposit":"53a41a74-9251-4f19-a899-3a7bd051b25c"},"_deposit":{"created_by":3,"id":"18807","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"18807"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00018807","sets":["14:2667:4374"]},"author_link":["31787"],"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"6","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2016)"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要（和文）：本研究では、縮環型立体保護基（Rind基）の立体効果を活用して新奇な低配位典型元素化合物を創製し、分子構造や物性、反応性について実験化学と理論化学とのインタープレイによって探究した。一連の高周期14族元素二価化学種「ジアリールテトリレン」を合成し、高度に分極した14族元素一酸素二重結合を有する「重いケトン」への合成変換を調査して、「ジアリールスタンニレン」の初合成を達成した。また、ゲルマノンの酸素原子移動反応に基づき、従来にないゲルマニウム酸化触媒を開発して性能を調査した。領域内共同研究により、種々の感応性低配位化合物について探究し、遷移金属錯体や触媒配位子への応用について調査した。\n研究成果の概要（英文）：In this study, we investigated the synthesis, characterization, and reactivity of stimuli-responsive low-coordinate compounds of main group elements by taking advantage of the steric effects of the fused-ring bulky Rind groups (Rind = 1,1,3,3,5,5,7,7-octa-R-substituted s-hydridacen-4-yl). A complete series of diaryltetrylenes, (Eind)2E: (E = Si, Ge, Sn, and Pb), were synthesized, and their molecular structures were confirmed by X-ray crystallography. The first diarylstannanone, (MPind)2Sn=O, was obtained by the reaction of (MPind) 2Sn: with N2O gas, whose X-ray structure exhibits a planar tricoordinate tin center with a very short Sn-O bond. We also examined the oxygen atom transfer (OAT) reaction of germanone, (Eind)2Ge=O, with isocyanide involving the cleavage of Ge-O bond and their application to the novel germanium catalytic system. We performed many joint researches of stimuli-responsive low-coordinate compounds and their application to the ligands for transition metal complexes.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：新学術領域研究（研究領域提案型）;  研究期間：2012～2016;   課題番号：24109003;   研究分野：応用元素化学;   科研費の分科・細目：","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PLANNED-24109003/"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"MATSUO, Tsukasa"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学理工学部; 准教授"}]},"item_8_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"Kindai University"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_be7fb7dd8ff6fe43","subitem_version_type":"NA"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"松尾, 司"},{"creatorName":"マツオ, ツカサ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"31787","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"90312800","nameIdentifierScheme":"研究者番号","nameIdentifierURI":" "}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-11-01"}],"displaytype":"detail","filename":"24109003seika.pdf","filesize":[{"value":"512.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"24109003seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/18807/files/24109003seika.pdf"},"version_id":"aea1f2c8-bb82-4655-a448-1cbc082b5402"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"低配位典型元素化合物","subitem_subject_scheme":"Other"},{"subitem_subject":"高周期14族元素","subitem_subject_scheme":"Other"},{"subitem_subject":"不飽和結合","subitem_subject_scheme":"Other"},{"subitem_subject":"感応性化学種","subitem_subject_scheme":"Other"},{"subitem_subject":"合成化学","subitem_subject_scheme":"Other"},{"subitem_subject":"テトリレン","subitem_subject_scheme":"Other"},{"subitem_subject":"酸素原子移動反応","subitem_subject_scheme":"Other"},{"subitem_subject":"典型元素触媒","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"感応性低配位典型元素化合物の創製と反応","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"感応性低配位典型元素化合物の創製と反応"},{"subitem_title":"Synthesis and Reactions of Stimuli-responsive Low-coordinate Compounds of Main Group Elements","subitem_title_language":"en"}]},"item_type_id":"8","owner":"3","path":["4374"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-11-01"},"publish_date":"2017-11-01","publish_status":"0","recid":"18807","relation_version_is_last":true,"title":["感応性低配位典型元素化合物の創製と反応"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T21:49:18.435178+00:00"}