{"created":"2023-06-20T16:47:09.707347+00:00","id":18791,"links":{},"metadata":{"_buckets":{"deposit":"dbf9e3a3-39d6-4de6-b900-26aeb6d09846"},"_deposit":{"created_by":3,"id":"18791","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"18791"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00018791","sets":["14:2667:4374"]},"author_link":["31752"],"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"4","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2016)"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要（和文）：ジオール類の保護基であるメチレンアセタールの新規変換反応について研究を行い、以下の成果を得た。（1）メチレンアセタールに対してフェニルチオトリメチルシランとN-ブロモスクシンイミドを作用させることで新規開裂反応が進行し、対応するブロモホルメート体が得られることを見いだした。（2）ブロモホルメート体をNaOMeで処理することにより、対応するエポキシド体へと変換することに成功し、さらにメチレンアセタール体からの一段階での変換にも成功した。（3）アミノアルコール由来のメチレンアセタール体でも同様の反応が進行することを見いだした。\n研究成果の概要（英文）：We developed a novel transformation reaction of methylene acetal using Phenylthiotrimethylsilane and N-bromosuccinimide. The reaction proceeded under mild conditions to afford the corresponding bromoformates, which could be converted to the corresponding epoxides by the treatment of NaOMe. This reaction was applicable to one-pot transformation from methylene acetal to eppoxide. The methylene acetal derived from aminoalcohol was also transformed under the same conditions giving the corresponding product.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：基盤研究(C);  研究期間：2014～2016;   課題番号：26460023;   研究分野：有機合成化学;   科研費の分科・細目：","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-26460023/"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"MAEGAWA, Tomohiro"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学薬学部; 准教授"}]},"item_8_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"Kindai University"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_be7fb7dd8ff6fe43","subitem_version_type":"NA"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"前川, 智弘"},{"creatorName":"マエガワ, トモヒロ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"31752","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"40363890","nameIdentifierScheme":"研究者番号","nameIdentifierURI":" "}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-11-01"}],"displaytype":"detail","filename":"26460023seika.pdf","filesize":[{"value":"298.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"26460023seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/18791/files/26460023seika.pdf"},"version_id":"52fcbec1-86b2-4cae-8cf7-adb653663a43"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"メチレンアセタール","subitem_subject_scheme":"Other"},{"subitem_subject":"エポキシド","subitem_subject_scheme":"Other"},{"subitem_subject":"N,O-アセタール","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"メチレンアセタールの新たな反応性の開拓とその複素環合成への応用","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"メチレンアセタールの新たな反応性の開拓とその複素環合成への応用"},{"subitem_title":"Development of novel reactivitity of methylene acetals and its application to synthesis of heterocycles","subitem_title_language":"en"}]},"item_type_id":"8","owner":"3","path":["4374"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-11-01"},"publish_date":"2017-11-01","publish_status":"0","recid":"18791","relation_version_is_last":true,"title":["メチレンアセタールの新たな反応性の開拓とその複素環合成への応用"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T21:49:46.324309+00:00"}