@article{oai:kindai.repo.nii.ac.jp:00018487,
 author = {谷嶋, 晃樹 and 安間, 晴穂 and 大久保, 貴志 and 前川, 雅彦 and 黒田, 孝義},
 issue = {29},
 journal = {理工学総合研究所研究報告, Annual reports by Research Institute for Science and Technology},
 month = {Feb},
 note = {Novel mixed-metal Cu(I)-Ni(Ⅱ) coordination polymers having an infinite one-dimensional (1D) structure, {[CuI5NiIⅡ5(Pip-dtc)2(C2H5CN)]・CHCl3}n (1) and {[CuI5CuⅡI5(Hm-dtc)2(C2H5CN)]・CHCl3}n (2) (Pip-dtc- = piperidine dithiocarbamate and Hm-dtc- = hexamethylene dithiocarbamate), have been prepared and structurally characterized via X-ray diffraction. These complexes comprised a mononuclear Ni(Ⅱ) unit, CuⅡL2, and a pentanuclear Cu(I) cluster unit, CuI5I5(C2H5CN)2. The energy states of these coordination polymers were investigated via photoelectron spectroscopy and diffuse reflectance spectroscopy, which indicated the formation of the narrow bands based on the weak orbital’s overlap between the mononuclear Ni(Ⅱ) unit and the pentanuclear Cu(I) cluster unit., application/pdf},
 pages = {11--16},
 title = {ヨウ化銅クラスターを骨格に含む新規混合金属一次元配位高分子の合成と結晶構造},
 year = {2017},
 yomi = {タニシマ, コウキ and アンマ, ハルホ and オオクボ, タカシ and マエカワ, マサヒコ and クロダ, タカヨシ}
}