{"created":"2023-06-20T16:46:38.458277+00:00","id":18151,"links":{},"metadata":{"_buckets":{"deposit":"ac7f004b-4354-49de-89d9-4ae43d315f24"},"_deposit":{"created_by":29,"id":"18151","owners":[29],"pid":{"revision_id":0,"type":"depid","value":"18151"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00018151","sets":["14:2667:4296"]},"author_link":["30573","30572","30571"],"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"6","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2015)"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要（和文）：セルロースの分解反応に用いたSiO2/[C1C4-SAim][OTf]、SiO2-SO3H、SiO2-S-[C3C4-SAim][OTf]は、いずれもセルロースを分解してHMFを生成した。また、反応後のSiO2-S- [C3C4-SAim][OTf]は、吸引ろ過により簡単に回収でき、大きな収率の低下なく2回反応に使用することができた。これにより共有結合型の酸性イオン液体-シリカハイブリッドにはセルロースの効果的な分解能力があり、かつ簡単な方法で容易に再利用可能であることが明らかとなった。本研究で開発した手法が、世界のエネルギー問題の解決に寄与することを期待する。\n研究成果の概要（英文）：We reported the conversion of cellulose into 5-(hydroxymethyl)furfural (HMF) utilizing acidic ionic liquids ([C3C4-SAim][OTf])-sillica gel hybrid catalysis. Microcrystalline cellulose was added [C4C1im][Cl] including acidic ionic liquids-sillica gel hybrid catalysis to give a homogeneous mixture. The solvent was kept at 120-130 ℃ with continuous stirring 6 h. HMF (9.0 %) was isolated. When the water was added in the reaction solvent, after the reaction, the acidic ionic liquids-sillica gel hybrid was separated out as the solid. As a results, it was possible to reuse the acidic ionic liquids-sillica gel hybrid two times easily. We expect that the methodlogy developed by this research contributes to a solution of world energy crisis.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：若手研究(Ｂ);  研究期間：2013～2015;   課題番号：25810109;   研究分野：有機化学;   科研費の分科・細目：","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25810109/"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"},{"subitem_text_value":"研究協力者"},{"subitem_text_value":"研究協力者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"KITAOKA, Satoshi"},{"subitem_text_language":"en","subitem_text_value":"NOBUOKA, Kaoru"},{"subitem_text_language":"en","subitem_text_value":"ISHIKAWA, Yuichi"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学工学部; 講師"},{"subitem_text_value":"大分大学工学部; 講師"},{"subitem_text_value":"大分大学工学部; 教授"}]},"item_8_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"Kindai University"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_be7fb7dd8ff6fe43","subitem_version_type":"NA"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"北岡, 賢"},{"creatorName":"キタオカ, サトシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"信岡, かおる"},{"creatorName":"ノブオカ, カオル","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"石川, 雄一"},{"creatorName":"イシカワ, ユウイチ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-10-15"}],"displaytype":"detail","filename":"25810109seika.pdf","filesize":[{"value":"385.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"25810109seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/18151/files/25810109seika.pdf"},"version_id":"ea28ce03-b5f1-448f-8679-fd47ef6d416d"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"イオン液体","subitem_subject_scheme":"Other"},{"subitem_subject":"グリーンケミストリー","subitem_subject_scheme":"Other"},{"subitem_subject":"バイオマス","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"強酸イオン液体ハイブリッドによる次世代エネルギーのブレイクスルー","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"強酸イオン液体ハイブリッドによる次世代エネルギーのブレイクスルー"},{"subitem_title":"Conversion of Cellulose into bio-fuels of next generation by acidic ionic liquids-sillica gel haybrid catalysis","subitem_title_language":"en"}]},"item_type_id":"8","owner":"29","path":["4296"],"pubdate":{"attribute_name":"公開日","attribute_value":"2016-10-15"},"publish_date":"2016-10-15","publish_status":"0","recid":"18151","relation_version_is_last":true,"title":["強酸イオン液体ハイブリッドによる次世代エネルギーのブレイクスルー"],"weko_creator_id":"29","weko_shared_id":-1},"updated":"2023-06-20T22:06:52.747128+00:00"}