{"created":"2023-06-20T16:46:33.847373+00:00","id":18068,"links":{},"metadata":{"_buckets":{"deposit":"04f31d51-373f-4433-9fb9-e635000b8711"},"_deposit":{"created_by":29,"id":"18068","owners":[29],"pid":{"revision_id":0,"type":"depid","value":"18068"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00018068","sets":["14:2667:4296"]},"author_link":["3269","3792"],"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"6","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2015)"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要（和文）：ターチオフェン連結C60（2-C60）と1-AuNP、2-C60と1-AgNPを用いて、フラーレンと金属ナノ粒子との複合体（Au-C60-PT-NT, Ag-C60-PT-NT）を合成した。走査型電子顕微鏡および、エネルギー分散型X線分析の結果、Au, Agの存在を確認するとともに、チューブ全体に金および銀ナノ粒子が凝集することなく分散している様子を観察した。さらに、これらハイブリッドナノチューブのラマンスペクトルを測定すると、金属ナノ粒子との複合体であるAu-C60-PT-NTおよびAg-C60-PT-NTは、2-C60-PT-NTと比較して顕著な表面増強ラマン散乱を示した。\n研究成果の概要（英文）：The novel hybrid nanotubes (2-C60-PT-NT, Ag-C60-PT-NT, and Au-C60-PT-NT) involves the following new aspects: i) the template-based electropolymerization of 2-C60 produced the fullerene C60-polythiophene NTs (2-C60-PT-NT) which showed the reversible redox behaviour of the fullerene C60, and ii) the plasmonic hybrid NTs (Ag-C60-PT-NT and Au-C60-PT-NT) show a significant SERS compared to that of the NTs (2-C60-PT-NT) which were prepared from the template-based electropolymerization of 2-C60. It is worth pointing out that our approach to preparing a metal-polymer NT composite completely differs from all previous studies on the deposition of metal NPs onto the surface of polymer NTs. We observed a fluorescence enhancement and photostability for the polythiophene of the hybrid NTs (1-Ag-PT-NT) in solution, while no enhancement of the polythiophene fluorescence was observed in the mixture of the polythiophene NTs (1-PT-NT) and terthiophene-modified silver NPs (1-AgNP).","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：基盤研究(C);  研究期間：2013～2015;   課題番号：25410215;   研究分野：有機無機ナノ複合化学;   科研費の分科・細目：","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25410215/"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"},{"subitem_text_value":"研究分担者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"FUJIHARA, Hisashi"},{"subitem_text_language":"en","subitem_text_value":"NAKAHODO, Tsukasa"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学理工学部; 教授"},{"subitem_text_value":"近畿大学理工学部; 講師"}]},"item_8_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"Kindai University"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_be7fb7dd8ff6fe43","subitem_version_type":"NA"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"藤原, 尚"},{"creatorName":"フジハラ, ヒサシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"3792","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"30190101","nameIdentifierScheme":"研究者番号","nameIdentifierURI":" "}]},{"creatorNames":[{"creatorName":"仲程, 司"},{"creatorName":"ナカホド, ツカサ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"3269","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"10375371","nameIdentifierScheme":"研究者番号","nameIdentifierURI":" "}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-10-17"}],"displaytype":"detail","filename":"25410215seika.pdf","filesize":[{"value":"653.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"25410215seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/18068/files/25410215seika.pdf"},"version_id":"caf3ffab-1cbd-4384-8bd9-f11ba99ee82c"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"ハイブリッド","subitem_subject_scheme":"Other"},{"subitem_subject":"有機無機ナノ材料","subitem_subject_scheme":"Other"},{"subitem_subject":"ナノチューブ","subitem_subject_scheme":"Other"},{"subitem_subject":"プラズモン","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"キラル有機無機ナノハイブリッドプラズモニクス材料の創製と機能","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"キラル有機無機ナノハイブリッドプラズモニクス材料の創製と機能"},{"subitem_title":"Synthesis and Function of Chiral Organic-Inorganic Nanohybrid Plasmonic Materials","subitem_title_language":"en"}]},"item_type_id":"8","owner":"29","path":["4296"],"pubdate":{"attribute_name":"公開日","attribute_value":"2016-10-17"},"publish_date":"2016-10-17","publish_status":"0","recid":"18068","relation_version_is_last":true,"title":["キラル有機無機ナノハイブリッドプラズモニクス材料の創製と機能"],"weko_creator_id":"29","weko_shared_id":-1},"updated":"2023-06-20T22:10:01.461951+00:00"}