{"created":"2023-06-20T16:43:09.771528+00:00","id":13966,"links":{},"metadata":{"_buckets":{"deposit":"b6964277-659c-48e3-8269-ce9f289380c0"},"_deposit":{"created_by":3,"id":"13966","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"13966"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00013966","sets":["14:2667:2671:2672"]},"author_link":["25632","25631"],"item_8_alternative_title_3":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Development of highly selective metal nanoparticle catalytic reaction in supercritic al carbon dioxide"}]},"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-01-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"5","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2013. )"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要(和文): 本研究では,  超臨界二酸化炭素と高い親和性を有する光学活性パラジウムナノ粒子を触媒に用い, 超臨界二酸化炭素中において不斉Suzuki-Miyaura cross coupling反応を検討した. さまざまな溶解補助剤と助触媒の組み合わせを検討した結果, エチレングリコールを溶解補助剤とし, 酸化銀を助触媒として用いることで, 有機溶媒中での反応と比べても, より高い反応性と反応選択性の両方が発現することを明らかにした.                研究成果の概要(英文): In this study, asymmetric Suzuki-Miyaura cross coupling reaction was discussed in supercritical carbon dioxide with optically-active Pd nanoparticles as a catalyst possessing specific affinity for supercritical carbon dioxide. Examination for various combinations of solubilization agent and co-catalyst resulted in both higher reactivity and higher selectivity comparing to the reaction in organic solvent when ethylene glycol and silver oxide were used as a solubilization agent and a co-catalyst respectively.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：基盤研究（C）;  研究期間：2011～2013;   課題番号：23550218;   研究分野：化学;   科研費の分科・細目：材料化学・有機工業材料","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/d/r/10375371.ja.html"}]},{"subitem_relation_name":[{"subitem_relation_name_text":"http://kaken.nii.ac.jp/d/r/30190101.ja.html"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"},{"subitem_text_value":"連携研究者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"NAKAHODO, Tsukasa"},{"subitem_text_language":"en","subitem_text_value":"FUJIHARA, Hisashi"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学理工学部; 講師"},{"subitem_text_value":"近畿大学理工学部; 教授"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"仲程,  司"},{"creatorName":"ナカホド, ツカサ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"藤原,  尚"},{"creatorName":"フジハラ, ヒサシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-03-31"}],"displaytype":"detail","filename":"KAKEN_23550218seika.pdf","filesize":[{"value":"120.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KAKEN_23550218seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/13966/files/KAKEN_23550218seika.pdf"},"version_id":"ee2157b6-2530-46d1-8aee-03ba82163c98"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"超臨界二酸化炭素","subitem_subject_scheme":"Other"},{"subitem_subject":"金属ナノ粒子","subitem_subject_scheme":"Other"},{"subitem_subject":"触媒","subitem_subject_scheme":"Other"},{"subitem_subject":"キラリティ","subitem_subject_scheme":"Other"},{"subitem_subject":"フッ化アルキル基","subitem_subject_scheme":"Other"},{"subitem_subject":"BINAP","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"超臨界二酸化炭素を反応場とする高選択的金属ナノ粒子触媒反応の開拓","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"超臨界二酸化炭素を反応場とする高選択的金属ナノ粒子触媒反応の開拓"}]},"item_type_id":"8","owner":"3","path":["2672"],"pubdate":{"attribute_name":"公開日","attribute_value":"2014-09-29"},"publish_date":"2014-09-29","publish_status":"0","recid":"13966","relation_version_is_last":true,"title":["超臨界二酸化炭素を反応場とする高選択的金属ナノ粒子触媒反応の開拓"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-06-20T23:06:24.254774+00:00"}