{"created":"2023-06-20T16:43:09.685560+00:00","id":13964,"links":{},"metadata":{"_buckets":{"deposit":"48253772-1a51-49f0-afdf-046b58fecdb8"},"_deposit":{"created_by":3,"id":"13964","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"13964"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00013964","sets":["14:2667:2671:2672"]},"author_link":["3791"],"item_8_alternative_title_3":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Developments of Functional Devices Using Iron Spin Crossover complexes With Large Cooperative Effects"}]},"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-01-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"5","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2013. )"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要(和文): qsal系三座Schiff塩基配位子による鉄(II)錯体において, 配位子上の置換基により, スピンクロスオーバー(SCO)特性が大きく変化することを明らかにした. 具体的には, カルボキシル基を有する[Fe(qsal-5c)2]においては, 2次元水素結合網の形成によりSCOを示すが, 置換位置の異なる[Fe(qsal-4c)2]や水酸基の置換した[Fe(qsal-nOH)2]系においてはSCOを示さないこと, また, ベンゼン環が付加したqnal系ではその置換位置の違いにより, qnal-21以外では配位子の平面性を保持するようなπ-π 相互作用が有効に働かず, SCOを示さないことがわかった.           研究成果の概要(英文): Substituent-effects on the spin crossover (SCO) property in the Fe (II)-qsal system have been thoroughly investigated. The complex with carboxylic acid [Fe(qsal-5c)2] show SCO phenomenon at 150 K with hysteresis of 21 K due to the 2-d hydrogen-bond network, while [Fe(qsal-4c)2] with it at different position and [Fe(qsal-n0H)2] (n = 3, 4, 5) with a hydroxyl group show no SCO phenomenon. Qnal-series having naphthalene moiety with different substituent positions, qnal-21, qnal-12, and qnal-32 were also investigated and only [Fe(qnal-21)2] shows SCO phenomenon. Single crystal X-ray analyses revealed that the pi-pi interaction is important factor to maintain the planarity of ligands, which strongly affects the ligand-field strength.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：基盤研究（C）;  研究期間：2011～2013;   課題番号：23550167;   研究分野：化学;   科研費の分科・細目：複合化学・機能物質化学","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/d/r/80257964.ja.html"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"KURODA, Takayoshi"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学理工学部; 教授"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"黒田,  孝義"},{"creatorName":"クロダ, タカヨシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"3791","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"80257964","nameIdentifierScheme":"研究者番号","nameIdentifierURI":" "}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-03-31"}],"displaytype":"detail","filename":"KAKEN_23550167seika.pdf","filesize":[{"value":"1.3 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KAKEN_23550167seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/13964/files/KAKEN_23550167seika.pdf"},"version_id":"62827105-a02e-4871-a3df-70fb80762a58"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"電気・磁気的機能","subitem_subject_scheme":"Other"},{"subitem_subject":"スピンクロスオーバー","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"大きな協同効果を示す鉄スピンクロスオーバー錯体を用いた機能デバイスの開発","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"大きな協同効果を示す鉄スピンクロスオーバー錯体を用いた機能デバイスの開発"}]},"item_type_id":"8","owner":"3","path":["2672"],"pubdate":{"attribute_name":"公開日","attribute_value":"2014-09-29"},"publish_date":"2014-09-29","publish_status":"0","recid":"13964","relation_version_is_last":true,"title":["大きな協同効果を示す鉄スピンクロスオーバー錯体を用いた機能デバイスの開発"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-06-20T23:06:26.752476+00:00"}