{"created":"2023-06-20T16:43:09.599488+00:00","id":13962,"links":{},"metadata":{"_buckets":{"deposit":"6a281c0e-e7a2-4f55-9cfc-cf641c5b0e75"},"_deposit":{"created_by":3,"id":"13962","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"13962"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00013962","sets":["14:2667:2671:2672"]},"author_link":["3466"],"item_8_alternative_title_3":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Efficient syntheses and functions of highly self—assembled metal lamacrocycles"}]},"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-01-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"5","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2013. )"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要(和文): 対アニオンの異なる前駆Cu(Ⅰ)錯体と, 4,4'-ビピリミジン関連配位子を用いて, 11種の新規なCu(Ⅰ)-{配位高分子・メタラマクロサイクリック}-{エチレン, カルボニル}付加体を合成し, その生成過程における対アニオンならびに合成溶媒の役割を系統的に明らかにした. これら新規化合物は, いずれも数少ないアニオンレセプターとなりうることが期待される. また, 自己組織化されたCu(Ⅰ)一{エチレン, カルボニル}付加体を単離・単結晶化できたことは, 化学吸着サイトの構築や触媒作用の発現などへの展開も期待できる.                研究成果の概要(英文): The C2H4 and CO adducts of novel Cu(I) coordination polymers and metallamacrocycles were self-assembled by the combinations of precursor Cu(I) complexes with different counter anions and the related 4,4'-bipyrimidine ligands. The roles of counter anions and reaction solvents were systematically proved in the formation processes. These new compounds are expected to become as a potential anion receptor.  In addition, polymeric Cu(I)-{C2H4, CO} adducts should be contributed to study the chemical adsorption and the catalytic reaction sites.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：基盤研究（C）;  研究期間：2011～2013;   課題番号：23550085;   研究分野：化学;   科研費の分科・細目：基礎化学・無機化学","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/d/r/70229293.ja.html"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"MAEKAWA, Masahiko"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学理工学総合研究所; 教授"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"前川,  雅彦"},{"creatorName":"マエカワ, マサヒコ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"3466","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"70229293","nameIdentifierScheme":"研究者番号","nameIdentifierURI":" "}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-03-31"}],"displaytype":"detail","filename":"KAKEN_23550085seika.pdf","filesize":[{"value":"311.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KAKEN_23550085seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/13962/files/KAKEN_23550085seika.pdf"},"version_id":"c7303203-85dc-4679-89e4-0d836853fa52"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Cu(Ⅰ)錯体","subitem_subject_scheme":"Other"},{"subitem_subject":"エチレン付加体","subitem_subject_scheme":"Other"},{"subitem_subject":"配位高分子","subitem_subject_scheme":"Other"},{"subitem_subject":"メタラマクロサイクリック","subitem_subject_scheme":"Other"},{"subitem_subject":"アニオンレセプター","subitem_subject_scheme":"Other"},{"subitem_subject":"自己組織化","subitem_subject_scheme":"Other"},{"subitem_subject":"分子認識","subitem_subject_scheme":"Other"},{"subitem_subject":"アニオンテンプレート","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"高度に自己組織化されたメタラマクロサイクリックの精密合成と機能","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"高度に自己組織化されたメタラマクロサイクリックの精密合成と機能"}]},"item_type_id":"8","owner":"3","path":["2672"],"pubdate":{"attribute_name":"公開日","attribute_value":"2014-09-29"},"publish_date":"2014-09-29","publish_status":"0","recid":"13962","relation_version_is_last":true,"title":["高度に自己組織化されたメタラマクロサイクリックの精密合成と機能"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-06-20T23:06:29.350986+00:00"}