{"created":"2023-06-20T16:43:09.556534+00:00","id":13961,"links":{},"metadata":{"_buckets":{"deposit":"b796cbb0-fc25-455e-8dee-b5aeb9147051"},"_deposit":{"created_by":3,"id":"13961","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"13961"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00013961","sets":["14:2667:2671:2672"]},"author_link":["3790"],"item_8_alternative_title_3":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Novel N-Containing pi-Conjugated Compounds: Synthesis, Physical Properties, and Functions"}]},"item_8_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-01-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"5","bibliographicPageStart":"1","bibliographic_titles":[{"bibliographic_title":"科学研究費助成事業研究成果報告書 (2013. )"}]}]},"item_8_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"研究成果の概要(和文): インドロ[ 3, 2, 1-jk ]カルバゾール(IC)と9,9'-ジフェニルー4,4', 5,5'-ビスカルバゾール(DBC)を基本骨格とした新規含窒素π共役化合物の合成, 物性の解明, 機能開発を目的とした. 合成物の発光特性を調べた結果, ICとその誘導体(三種)は, 何れの誘導体も溶液状態でICよりも発光極大波長が長波長シフトとし, 量子収率の増大が見られた. 固体状態における発光極大波長は, さらなる長波長シフトが観測されたが, 量子収率は一種のみに増大が見られた. 一方, DBCとその誘導体(二種)は, 溶液状態・固体状態ともに誘導化での発光特性の向上は見られなかった.          研究成果の概要(英文): The creation of highly fluorescent materials should be an urgent and significant subject. For this purpose, we designed the novel pi-conjugated compounds having indro[3,2,1-jk]carbazole (IC) and 9, 9' -diphenyl-4, 4' , 5, 5' -biscarbazole (DBC) as a framework, synthesized them, and elucidated their photophysical properties and functions. We investigated the photophysical properties of synthesized compounds. As a result, the bathochromic shift of the fluorescence maximum and the increase of quantum yield in three IC derivatives were observed by comparison with those of IC in solution state. In solid state, although the further bathochromic shift of the fluorescence maximum of all IC derivatives were observed, the only one IC derivative showed the increase of quantum yield. On the other hand, neither of the bathochromic shift of the fluorescence maximum an d the increase of quantum yield in two DBC derivatives were observed by comparison with those of DBC in solution and solid state.","subitem_description_type":"Abstract"}]},"item_8_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究種目：基盤研究（C）;  研究期間：2011～2013;   課題番号：23550062;   研究分野：化学;   科研費の分科・細目：基礎化学・有機化学","subitem_description_type":"Other"}]},"item_8_description_37":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Research Paper","subitem_description_type":"Other"}]},"item_8_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_8_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学"}]},"item_8_relation_11":{"attribute_name":"著者 外部リンク","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/d/r/30200637.ja.html"}]}]},"item_8_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"}]},"item_8_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"YAMAGUCHI, Yoshihiro"}]},"item_8_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学理工学部; 教授"}]},"item_8_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"山ロ,  仁宏"},{"creatorName":"ヤマグチ, ヨシヒロ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"3790","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"30200637","nameIdentifierScheme":"研究者番号","nameIdentifierURI":" "}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-03-31"}],"displaytype":"detail","filename":"KAKEN_23550062seika.pdf","filesize":[{"value":"356.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KAKEN_23550062seika.pdf","url":"https://kindai.repo.nii.ac.jp/record/13961/files/KAKEN_23550062seika.pdf"},"version_id":"20367991-64e9-4851-afe0-1d4db002c26b"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"含窒素化合物","subitem_subject_scheme":"Other"},{"subitem_subject":"π共役系","subitem_subject_scheme":"Other"},{"subitem_subject":"有機合成","subitem_subject_scheme":"Other"},{"subitem_subject":"物性","subitem_subject_scheme":"Other"},{"subitem_subject":"機能","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"含窒素新規π共役系化合物の合成、物性および機能","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"含窒素新規π共役系化合物の合成、物性および機能"}]},"item_type_id":"8","owner":"3","path":["2672"],"pubdate":{"attribute_name":"公開日","attribute_value":"2014-09-29"},"publish_date":"2014-09-29","publish_status":"0","recid":"13961","relation_version_is_last":true,"title":["含窒素新規π共役系化合物の合成、物性および機能"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-06-20T23:06:31.109588+00:00"}