{"created":"2023-06-20T16:43:02.233907+00:00","id":13814,"links":{},"metadata":{"_buckets":{"deposit":"9257a61f-7a9a-4569-8fe5-371c40e1e386"},"_deposit":{"created_by":3,"id":"13814","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"13814"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00013814","sets":["14:923:2261:2269","21:3039:3842:3845"]},"author_link":["25282","25281","25283","25280"],"item_2_alternative_title_3":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Preparation of Poly(methyl methacrylate-co-1H,1H,7H- dodecafluoroheptyl methacrylate) Microspheres as Biomedical Materials"}]},"item_2_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2012-06-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"46","bibliographicPageStart":"39","bibliographicVolumeNumber":"3","bibliographic_titles":[{"bibliographic_title":"近畿大学次世代基盤技術研究所報告"},{"bibliographic_title":"Kinki University Research Institute of Fundamental Technology for Next Generation","bibliographic_titleLang":"en"}]}]},"item_2_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"[Abstract] Emulsion copolymerization of methyl methacrylate (MMA) and 1H,1H,7H- dodecafluoroheptyl methacrylate (DFHMA) yielded a series of copolymer microspheres, poly (MMA-co-DFH MA) with varying the molar ratio of the DFHMA moiety. Potassium peroxodisulfate(KPS) wasused as an initiator. The molar ratio in feed was varied as MMA : MFHMA =1.0 : 0.0, 0.95 : 0.05, 0.90 : 0.10, 0.85 :0.15 and 0.80 : 0.20. The resulting copolymer microspheres were characterized by scanning electron microscope (SEM). It was found that diameter ( d ) of poly(MMA-co-DFHMA)s increases from 90.0±104nm to 144.0±88nm with increasing the amount of DFHMA in feed, where d is determined by means of laser diffraction particle size analyzer. Poly(MMA-co-DFHMA)s were found to increase the contact angle of water (θ= 106°) and colza-oil (θ= 89°) compared with poly(methyl methacrylate)(PMMA). It was also confirmed from a cell culture test that the polymer films prepared from poly(MMA-co-DFHMA) showed an effective suppression of adhesiveness of HeLa cell.","subitem_description_type":"Abstract"}]},"item_2_description_36":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Mitsui, Syo","subitem_description_type":"Other"}]},"item_2_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学次世代基盤技術研究所"}]},"item_2_source_id_22":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"21858802","subitem_source_identifier_type":"ISSN"}]},"item_2_text_10":{"attribute_name":"著者 役割","attribute_value_mlt":[{"subitem_text_value":"研究代表者"},{"subitem_text_value":"共同研究者"},{"subitem_text_value":"共同研究者"},{"subitem_text_value":"共同研究者"}]},"item_2_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Sugiyama, Kazuo"},{"subitem_text_language":"en","subitem_text_value":"Mitsui, Sho"},{"subitem_text_language":"en","subitem_text_value":"Shiraishi, Kohei"},{"subitem_text_language":"en","subitem_text_value":"Hisanaga, Naokatu"}]},"item_2_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"近畿大学工学部生物化学工学科; 特任教授"},{"subitem_text_value":"近畿大学工学部生物化学工学科"},{"subitem_text_value":"近畿大学工学部生物化学工学科; 教授"},{"subitem_text_value":"サンユレック株式会社"}]},"item_2_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"Kinki University"},{"subitem_text_value":"Kinki University"},{"subitem_text_value":"Kinki University"}]},"item_2_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"杉山,  一男"},{"creatorName":"スギヤマ, カズオ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"三井,  翔"},{"creatorName":"ミツイ, ショウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"白石,  浩平"},{"creatorName":"シライシ, コウヘイ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"久永,  直克"},{"creatorName":"ヒサナガ, ナオカツ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-19"}],"displaytype":"detail","filename":"AA12517632-20120600-0039.pdf","filesize":[{"value":"1.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"AA12517632-20120600-0039.pdf","url":"https://kindai.repo.nii.ac.jp/record/13814/files/AA12517632-20120600-0039.pdf"},"version_id":"4fe9a6e8-b87a-4431-80bf-cb0efe7e5bc5"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"〈原著論文〉生医学材料としての含フッ素ポリマーナノ粒子の調製","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"〈原著論文〉生医学材料としての含フッ素ポリマーナノ粒子の調製"}]},"item_type_id":"2","owner":"3","path":["2269","3845"],"pubdate":{"attribute_name":"公開日","attribute_value":"2013-01-24"},"publish_date":"2013-01-24","publish_status":"0","recid":"13814","relation_version_is_last":true,"title":["〈原著論文〉生医学材料としての含フッ素ポリマーナノ粒子の調製"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-06-20T23:09:43.870135+00:00"}