@article{oai:kindai.repo.nii.ac.jp:00013787, author = {杉山, 一男 and 中村, 豪希 and 白石, 浩平 and 久永, 直克}, journal = {近畿大学次世代基盤技術研究所報告, Kinki University Research Institute of Fundamental Technology for Next Generation}, month = {Jun}, note = {[Abstract] Emulsion copolymerization of methyl methacrylate(MMA) and 1H,1H,2H,2H-heptadecafluorodecyl acrylate (FDA) yielded a series of copolymer microspheres, poly (MMA-co-FDA) ,with varying content of the FDA moiety. Potassium peroxodisulfate (KPS) was used as an initiator. The resulting copolymer microspheres were characterized by scanning electron microscope(SEM).poly(MMA-co-FDA)s with the molar ratio in feed MMA : FDA = 0.9 : 0.1 have diameters d = 873±500 nm and d = 71±24 nm of diameter by varying the amount of monomers in feed, where d is determined by means of SEM image. The particles poly (MMA-co-FDA) were found to increase the contact angle of water (θ= 106°) and colza-oil (θ= 89°) compared with poly (methyl methacrylate) (PMMA) and Teflon. It was confirmed from the contact angle that the introduction of fluorine atoms into PMMA results in preventing from the pollution., application/pdf}, pages = {37--44}, title = {〈原著論文〉防汚フィルム用含フッ素ポリマーナノ粒子の調製とフィルムの作成}, volume = {2}, year = {2011}, yomi = {スギヤマ, カズオ and ナカムラ, ゴウキ and シライシ, コウヘイ and ヒサナガ, ナオカツ} }