@article{oai:kindai.repo.nii.ac.jp:00012934,
 author = {鈴木, 隆 and 枝, 和男},
 journal = {近畿大学工業高等専門学校研究紀要, Research reports Kinki University Technical College},
 month = {Mar},
 note = {Two types of lower molybdenum oxides, such as orthorhombic and monoclinic Mo_4O_11, were synthesized from the stoichiometric mixtures with the molar ratio of MoO_0.347 / MoO_3 = 0.104 under controlled temperature. Mo_4O_11 crystallizes in two different structures were depending upon the temperature of preparation, blow 890 K the monoclinic was obtained and above this temperature the orthorhombic was formed. The heats of reaction of these materials, MoO_2 and MoO_3 dissolved in strong base solution contained K_3[Fe(CN)_6] were measured directly by using of the conduction calorimeter. By using these direct measured data, the standard enthalpies of formation of orthorhombic and monoclinic Mo_4O_11 were determined indirectly by means of Hess's law of the summation. It was revealed that the A_fH^o of the orthorhombic Mo_4O_11 was lower than that of monoclinic one. The results will be reported in details., application/pdf},
 pages = {97--99},
 title = {低次モリブデン酸化物の熱力学的研究},
 volume = {8},
 year = {2015},
 yomi = {スズキ, タカシ and エダ, カズオ}
}