| Item type |
☆紀要論文 / Departmental Bulletin Paper(1) |
| 公開日 |
2015-06-09 |
| タイトル |
|
|
タイトル |
Role of bulky thiophenylether substituted aromatic compounds as a linker in porous silver(I) coordination polymers |
|
言語 |
en |
| 著者 |
Suenaga, Yusaku
Ueda, Shyogo
Umehata, Yukiko
Maekawa, Masahiko
|
| 言語 |
|
|
言語 |
eng |
| キーワード |
|
|
主題 |
silver(I) coordination polymer, X-ray crystal structures, porous structure, thioether substituted aromatic compounds, absorption-desorption behavior |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
departmental bulletin paper |
| 著者 所属 |
|
|
値 |
近畿大学 |
| 著者 所属 |
|
|
値 |
近畿大学 |
| 著者 所属 |
|
|
値 |
近畿大学 |
| 著者 所属 |
|
|
値 |
近畿大学理工学総合研究所 |
| 著者所属(翻訳) |
|
|
値 |
Department of Science, Kinki University |
| 著者所属(翻訳) |
|
|
値 |
Department of Science, Kinki University |
| 著者所属(翻訳) |
|
|
値 |
Department of Science, Kinki University |
| 著者所属(翻訳) |
|
|
値 |
Research Institute for Science and Technology, Kinki University |
| 版 |
|
|
出版タイプ |
VoR |
|
出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| 出版者 名前 |
|
|
出版者 |
近畿大学理工学総合研究所 |
| 書誌情報 |
理工学総合研究所研究報告
en : Annual reports by Research Institute for Science and Technology
巻 27,
p. 25-34,
発行日 2015-02-01
|
| ISSN |
|
|
収録物識別子タイプ |
ISSN |
|
収録物識別子 |
09162054 |
| 抄録 |
|
|
内容記述タイプ |
Abstract |
|
内容記述 |
[Abstract]Three silver(I) coordination polymers, [Ag_2(tphb)(C_4F_8(COO)_2)(THF)]_n (1, tphb = 1, 2, 4, 5-tetrakis(phenylsulfanyl)-benzene), {[Ag_6(hphb)_2(C_4F_8(COO)_2)_3(THF)_6](THF)_2}_n (2, hphb = hexakis(phenylsulfanyl)benzene) and {[Ag_2(ophn)-(C_6F_12(COO)_2)](THF)_2}_n (3, ophn = octakis(phenylsulfanyl)naphthalene) have been prepared and their molecular structures determined by X-ray crystallography. In 1, tphb plays a role as an intra-molecular linker in [C_4F_8(COOAg)_2]_n, the coordination polymer forming a linear structure having a double chain. In 2, hphb acts as an inter-molecular linker between linear chain consisting of silver ion and perfluorodicarboxylic acid, which together form a two dimensional sheet structure. On the other hand, in 3, ophn molecules function as inter-molecular linkers, similar to complex 2; however, 3 has a three dimensional structure due to the distorted naphthalene ring of ophn. In addition, the structure of complex 3 is porous and shows absorption-desorption behavior for a guest molecule (THF) in the cavity. |
| フォーマット |
|
|
内容記述タイプ |
Other |
|
内容記述 |
application/pdf |
AN10074306-20150228-0025.pdf (4.6 MB)
