{"created":"2023-06-20T16:40:49.360683+00:00","id":11196,"links":{},"metadata":{"_buckets":{"deposit":"d01de10e-60b5-413e-ad05-c9d3dc85c3f6"},"_deposit":{"created_by":3,"id":"11196","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"11196"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00011196","sets":["14:923:2091:2135","21:3039:3558:3572"]},"author_link":["21594","21595"],"item_2_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1989-01-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"19","bibliographicPageStart":"15","bibliographicVolumeNumber":"1","bibliographic_titles":[{"bibliographic_title":"理工学総合研究所研究報告"},{"bibliographic_title":"Annual reports by Research Institute for Science and Technology","bibliographic_titleLang":"en"}]}]},"item_2_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A new spectrophotometric method for the determination of cobalt(II) with 2,5-bis-(2-picolylamino)-1,4-benzoquinone (PABQ) in the presence of sodium L-ascorbate is proposed. PABQ is prepared by refluxing a 1 : 2 mixture of 1,4-benzoquinone and 2-aminomethylpyridine in ethanol. PABQ reacts with cobalt(II) to form a water soluble complex which has an absorption maximum at 560 nm. The calibration curve obeys Beer's law over the concentration range from 0.1 to 2μg/ml of cobalt(II). The apparent molar absorption coefficient is 3.7×10^4dm^3 mol^<-1>cm^<-1>. The recommended procedure is as follows; To a sample solution, 1 ml of 10% sodium L-ascorbate and 5 ml of 10^<-3>M PABQ methanol solution is added, pH is adjusted to 6.5〜7.5 with ammonium acetate solution, and the solution is made up to 50 ml with water. After standing the solution for 15〜20 min, the absorbance is measured at 560 nm against reagent blank.","subitem_description_type":"Abstract"}]},"item_2_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学理工学総合研究所"}]},"item_2_source_id_22":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09162054","subitem_source_identifier_type":"ISSN"}]},"item_2_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"KATO, Takeshi"},{"subitem_text_language":"en","subitem_text_value":"NAKAYAMA, Tatsuro"}]},"item_2_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"Research Institute for Science and Technology, Kinki University"},{"subitem_text_value":"Department of Applied Chemistry, Faculty of Science and Technology, Kinki University"}]},"item_2_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"近畿大学理工学総合研究所"},{"subitem_text_value":"近畿大学理工学部応用化学科"}]},"item_2_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"加藤,  武"},{"creatorName":"カトウ, タカシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"21594","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"中山,  達郎"},{"creatorName":"ナカヤマ, タツロウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"21595","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-19"}],"displaytype":"detail","filename":"AN10074306-19890100-0015.pdf","filesize":[{"value":"253.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"AN10074306-19890100-0015.pdf","url":"https://kindai.repo.nii.ac.jp/record/11196/files/AN10074306-19890100-0015.pdf"},"version_id":"15742590-9e38-46d7-8cad-30bcff32813d"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"spectrophotometry","subitem_subject_scheme":"Other"},{"subitem_subject":"determination of cobalt(II)","subitem_subject_scheme":"Other"},{"subitem_subject":"2,5-bis-(2-picolylamino)-1","subitem_subject_scheme":"Other"},{"subitem_subject":"4-benzoquinone","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"2,5-ビス-(2-ピコリルアミノ)-1,4-ベンゾキノンを用いるコバルト(II)の吸光光度定量","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"2,5-ビス-(2-ピコリルアミノ)-1,4-ベンゾキノンを用いるコバルト(II)の吸光光度定量"},{"subitem_title":"Spectrophotometric Determination of Cobalt (II) with 2,5-Bis-(2-picolylamino)-1,4-benzoquinone","subitem_title_language":"en"}]},"item_type_id":"2","owner":"3","path":["2135","3572"],"pubdate":{"attribute_name":"公開日","attribute_value":"2015-03-10"},"publish_date":"2015-03-10","publish_status":"0","recid":"11196","relation_version_is_last":true,"title":["2,5-ビス-(2-ピコリルアミノ)-1,4-ベンゾキノンを用いるコバルト(II)の吸光光度定量"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T20:47:38.443146+00:00"}