{"created":"2023-06-20T16:40:47.680599+00:00","id":11161,"links":{},"metadata":{"_buckets":{"deposit":"144ad9e9-5ccf-41f4-80e3-d4647ab76973"},"_deposit":{"created_by":3,"id":"11161","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"11161"},"status":"published"},"_oai":{"id":"oai:kindai.repo.nii.ac.jp:00011161","sets":["14:923:2091:2097","21:3039:3558:3569"]},"author_link":["21512","21514","21513","21511","21510","21509"],"item_2_biblio_info_21":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-02-01","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"19","bibliographicPageStart":"11","bibliographicVolumeNumber":"25","bibliographic_titles":[{"bibliographic_title":"理工学総合研究所研究報告"},{"bibliographic_title":"Annual reports by Research Institute for Science and Technology","bibliographic_titleLang":"en"}]}]},"item_2_description_33":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"[Abstract] Two isocyano-coordinated cobalt(III)-Schiff base complexes, [Co(L1)(CH_3OH)(NC)]・CH_2Cl_2 (1) and [Co(L2)(H_2O)(NC)]•CH_2Cl_2  (2) (H_2L1＝ N,N-disalicylidene-2,3-naphthalenediimine, H_2L2  ＝ N,N-bis(3-methoxysalicylaldehyde)-1,2-phenylene-diimine), were synthesized from the reaction of TCNQ and corresponding planar cobalt(II) complexes 3 and 4, respectively. The single-crystal X-ray diffraction analysis of the crystals clearly shows the coordination of C1^- moiety to the Co(III) complex. The characterization of products by the FT-IR and C^<13> NMR measurements indicate the coexistence of two isomers, isocyano and cyano complexes, both in the solid state and in solution. The DFT calculations on the isomerization reaction (ΔH_<iso>: -42.6 kJ mot^<-1>, E_a: 121.3 kJ mol^<-1>) indicate the difficulty of the reaction at room temperature, which is in accordance with the observation of the two isomers.","subitem_description_type":"Abstract"}]},"item_2_description_41":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_publisher_14":{"attribute_name":"出版者 名前","attribute_value_mlt":[{"subitem_publisher":"近畿大学理工学総合研究所"}]},"item_2_source_id_22":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09162054","subitem_source_identifier_type":"ISSN"}]},"item_2_text_7":{"attribute_name":"著者(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"&EMPTY&"},{"subitem_text_language":"en","subitem_text_value":"黒田, 孝義"},{"subitem_text_language":"en","subitem_text_value":"&EMPTY&"},{"subitem_text_language":"en","subitem_text_value":"&EMPTY&"},{"subitem_text_language":"en","subitem_text_value":"大久保, 貴志"},{"subitem_text_language":"en","subitem_text_value":"前川, 雅彦"}]},"item_2_text_8":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"Department of Chemistry, School of Science and Engineering, Kinki University"},{"subitem_text_value":"Department of Chemistry, School of Science and Engineering, Kinki University"},{"subitem_text_value":"Department of Chemistry, School of Science and Engineering, Kinki University"},{"subitem_text_value":"Department of Chemistry, School of Science and Engineering, Kinki University"},{"subitem_text_value":"Department of Chemistry, School of Science and Engineering, Kinki University"},{"subitem_text_value":"Department of Chemistry, School of Science and Engineering, Kinki University"}]},"item_2_text_9":{"attribute_name":"著者所属(翻訳)","attribute_value_mlt":[{"subitem_text_value":"近畿大学"},{"subitem_text_value":"近畿大学"},{"subitem_text_value":"近畿大学"},{"subitem_text_value":"近畿大学"},{"subitem_text_value":"近畿大学"},{"subitem_text_value":"近畿大学"}]},"item_2_version_type_12":{"attribute_name":"版","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yu,  Zhong"},{"creatorName":"&EMPTY&","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kuroda-Sowa,  Takayoshi"},{"creatorName":"クロダ-ソワ, タカヨシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Okamoto,  Akihiro"},{"creatorName":"オカモト, アキヒロ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nabei,  Atsuhiro"},{"creatorName":"ナベイ, アツヒロ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Okubo,  Takashi"},{"creatorName":"オオクボ, タカシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Maekawa,  Masahiko"},{"creatorName":"マエカワ, マサヒコ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-19"}],"displaytype":"detail","filename":"AN10074306-20130228-0011.pdf","filesize":[{"value":"844.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"AN10074306-20130228-0011.pdf","url":"https://kindai.repo.nii.ac.jp/record/11161/files/AN10074306-20130228-0011.pdf"},"version_id":"0abb6858-2eee-460c-ad1c-abe50fc597b9"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Cobalt Schiff base complex","subitem_subject_scheme":"Other"},{"subitem_subject":"Isocyano group","subitem_subject_scheme":"Other"},{"subitem_subject":"DFT calculation","subitem_subject_scheme":"Other"},{"subitem_subject":"X-ray crystal structures","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"The observation of isocyano cobalt (III)-Schiff base complexes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"The observation of isocyano cobalt (III)-Schiff base complexes","subitem_title_language":"en"}]},"item_type_id":"2","owner":"3","path":["2097","3569"],"pubdate":{"attribute_name":"公開日","attribute_value":"2013-06-28"},"publish_date":"2013-06-28","publish_status":"0","recid":"11161","relation_version_is_last":true,"title":["The observation of isocyano cobalt (III)-Schiff base complexes"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T20:42:12.240235+00:00"}