@article{oai:kindai.repo.nii.ac.jp:00011161,
 author = {Yu,  Zhong and Kuroda-Sowa,  Takayoshi and Okamoto,  Akihiro and Nabei,  Atsuhiro and Okubo,  Takashi and Maekawa,  Masahiko},
 journal = {理工学総合研究所研究報告, Annual reports by Research Institute for Science and Technology},
 month = {Feb},
 note = {[Abstract] Two isocyano-coordinated cobalt(III)-Schiff base complexes, [Co(L1)(CH_3OH)(NC)]・CH_2Cl_2 (1) and [Co(L2)(H_2O)(NC)]•CH_2Cl_2  (2) (H_2L1＝ N,N-disalicylidene-2,3-naphthalenediimine, H_2L2  ＝ N,N-bis(3-methoxysalicylaldehyde)-1,2-phenylene-diimine), were synthesized from the reaction of TCNQ and corresponding planar cobalt(II) complexes 3 and 4, respectively. The single-crystal X-ray diffraction analysis of the crystals clearly shows the coordination of C1^- moiety to the Co(III) complex. The characterization of products by the FT-IR and C^<13> NMR measurements indicate the coexistence of two isomers, isocyano and cyano complexes, both in the solid state and in solution. The DFT calculations on the isomerization reaction (ΔH_<iso>: -42.6 kJ mot^<-1>, E_a: 121.3 kJ mol^<-1>) indicate the difficulty of the reaction at room temperature, which is in accordance with the observation of the two isomers., application/pdf},
 pages = {11--19},
 title = {The observation of isocyano cobalt (III)-Schiff base complexes},
 volume = {25},
 year = {2013},
 yomi = {クロダ-ソワ, タカヨシ and オカモト, アキヒロ and ナベイ, アツヒロ and オオクボ, タカシ and マエカワ, マサヒコ}
}