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        <identifier>oai:kindai.repo.nii.ac.jp:02001904</identifier>
        <datestamp>2024-11-25T02:35:25Z</datestamp>
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          <dc:title xml:lang="ja">ジチオナイト錯体によるメカニカル結晶の開発</dc:title>
          <dc:title xml:lang="en">Development of mechanical crystals using dithionite complexes</dc:title>
          <jpcoar:creator>
            <jpcoar:nameIdentifier nameIdentifierScheme="e-Rad">70377399</jpcoar:nameIdentifier>
            <jpcoar:creatorName xml:lang="ja">中井, 英隆</jpcoar:creatorName>
            <jpcoar:creatorName xml:lang="en">NAKAI, Hidetaka</jpcoar:creatorName>
            <jpcoar:affiliation>
              <jpcoar:nameIdentifier nameIdentifierScheme="kakenhi">34419</jpcoar:nameIdentifier>
              <jpcoar:affiliationName xml:lang="ja">近畿大学</jpcoar:affiliationName>
              <jpcoar:affiliationName xml:lang="en">Kindai University</jpcoar:affiliationName>
            </jpcoar:affiliation>
          </jpcoar:creator>
          <jpcoar:subject xml:lang="ja" subjectScheme="Other">合成化学</jpcoar:subject>
          <jpcoar:subject xml:lang="ja" subjectScheme="Other">光物性</jpcoar:subject>
          <jpcoar:subject xml:lang="ja" subjectScheme="Other">メカニカル結晶</jpcoar:subject>
          <jpcoar:subject xml:lang="ja" subjectScheme="Other">有機金属錯体</jpcoar:subject>
          <jpcoar:subject xml:lang="ja" subjectScheme="Other">ジチオナイト錯体</jpcoar:subject>
          <datacite:description xml:lang="ja" descriptionType="Abstract">合目的的にメカニカル結晶を開発することを目的として、ジチオナイト錯体の結晶が示す「2つのメカニカル機能(光照射によって、結晶が屈曲する機能と弾ける機能)」に着目し、新規なジチオナイト錯体の設計・合成を中心に研究を進めた。その結果、種々の置換基を有する新規ジチオナイト錯体およびジチオナイト錯体の類縁錯体の合成に成功し、メカニカル材料の創製につながる「メカニカル機能の諸特性と分子・結晶構造との相関」に対する知見を得ることができた。</datacite:description>
          <datacite:description xml:lang="en" descriptionType="Abstract">With the aim of purposefully developing mechanical crystals, we have focused on the “two mechanical functions (bending and jumping of the crystals upon light irradiation)” exhibited by dithionite complex crystals, and have conducted research mainly on the design and synthesis of new dithionite complexes. As a result, we have succeeded in synthesizing new dithionite complexes with various substituents and a new analogous complex of dithionite complex, and have obtained knowledge on the “correlation between various properties of mechanical functions and molecular/crystal structures” that will lead to the creation of mechanical materials.</datacite:description>
          <datacite:description xml:lang="ja" descriptionType="Other">研究分野：錯体化学</datacite:description>
          <dc:language>jpn</dc:language>
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          <oaire:version rdf:resource="http://purl.org/coar/version/c_970fb48d4fbd8a85">VoR</oaire:version>
          <jpcoar:identifier identifierType="URI">https://kindai.repo.nii.ac.jp/records/2001904</jpcoar:identifier>
          <jpcoar:fundingReference>
            <jpcoar:funderName xml:lang="ja">独立行政法人日本学術振興会</jpcoar:funderName>
            <jpcoar:funderName xml:lang="en">Japan Society for the Promotion of Science</jpcoar:funderName>
            <datacite:awardNumber awardURI="https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21K05103/">21K05103</datacite:awardNumber>
            <jpcoar:awardTitle xml:lang="ja">ジチオナイト錯体によるメカニカル結晶の開発</jpcoar:awardTitle>
            <jpcoar:awardTitle xml:lang="en">Development of mechanical crystals using dithionite complexes</jpcoar:awardTitle>
          </jpcoar:fundingReference>
          <jpcoar:sourceTitle xml:lang="ja">科学研究費助成事業研究成果報告書 (2023)</jpcoar:sourceTitle>
          <jpcoar:numPages>8</jpcoar:numPages>
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